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http://dx.doi.org/10.5229/JKES.2004.7.1.016

Deposition of Alkali Metal Ions at Polypyrrole Film Electrodes Modified with Fullerene  

Cha Seong-Keuck (Division of Chemistry, Kyungnam University)
Lee Sangchun (Division of Chemistry, Kyungnam University)
Publication Information
Journal of the Korean Electrochemical Society / v.7, no.1, 2004 , pp. 16-20 More about this Journal
Abstract
To electropolymerize Polypyrrole(ppy) film modified with fullerene $ions(full^-)$ the cell, Au/5 mM pyrrole, 1mM fullerene, 0.1M $TBABF_4,\;CH_2Cl_2/Pt$, was employed to Prepare the wafer-like type of $electrode/ppy(full^-)ppy(full^-){\ldots}$ electrodes. They were applied to deposit alkali metal ions with the cell of Au(quartz crystal analyzer; QCA)/ppy$(full^-)$, 0.01M metal ion(aq.)/Pt. The depositing rate constant of each ion for $Li^+,\;Na^+,\;K^+,\;Rb^+\;and\;Cs^+$, determined from the first order equation was $1.60\times10^{-8},\;3.13\times10^{-11},\;1.38\times10^{-9},\;2.71\times10^{-11}\;and\;2.98\times10^{-12}mo1.s^{-1}$ respectively. The calculated stoichiometry of the ions determined by quartz crystal microbalance(QCM) at the electrodes was $Li_7C_{60},\;Na_4C_{60},\;K_3C_{60},\;Rb_1C_{60}\;and\;Cs_1C_{60}$ respectively.
Keywords
Fullerene; Ppy; Electropolymerization; Deposition of metal ions;
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1 T. Akasaka, and W. Ando, J. Am. Chem. Soc., 115, 1605 (1993)   DOI
2 D. Dubois, and K. M. Kadish, J. Am. Chem. Soc., 113, 7773 (1991)   DOI
3 A.Deronzer, and J. C. Muoutet, J. Am. Chem. Soc., 116, 5010 (1994)
4 D. A. Buttry, and M. D. Ward, Chem. Rev., 92, 1355 (1992)   DOI
5 S. Ruth, H. Blerier and W. Pukaki, Faraday Discuss Chem. Soc. 88, 223 (1989)   DOI
6 R. F. Lane, and A. T.Hubbard, J. Phys. Chem., 77, 1401 (1973)   DOI
7 Murray, R. W., 'Electroanalytical Chemistry,' vol.(13), Marcel Dekker, NY. p.191 (1984)
8 R. D. Rocklin, and R. W. Murray, J. Electroanal. Chem., 100, 271 (1979)   DOI   ScienceOn
9 S. K Cha, J. Polymer Sci. part B, 35, 165 (1997)   DOI   ScienceOn
10 W. S. Kim, H. S. Song, and B. O. Lee, Macromo. Res., 10(5), (2002)
11 C.-W. Lee, J.-H. Yoon, H. W. Cho, S. E. Bae and K.-B. Lee, J. Kor. Electrochem. Soc., 5(4), 202 (2002)   DOI   ScienceOn
12 H. D. Abruna, and A. J. Bard, J. Am. Chem. Soc., 103, 6898 (1980)
13 M. S. Wrighton, R. G. Austin, A. B. Bocarsly, J. M. Bolts, O. Haas, K. D. Legg, L. Nadjo, and M. C. Palazzotto, J. Am. Chem. Soc., 100, 7264 (1978)   DOI
14 H. W. Kroto, J. R. Heath, S. C. O'Brien, R. F. Curl, and R. E. Smally, Nature, 318, 162 (1985)   DOI
15 K. S. Jang, B. Moon, E. J. Oh, J. -H. Hong, J. Kor. Electrochem. Soc., 6(2), 134 (2003)   과학기술학회마을   DOI   ScienceOn
16 W. Kratschmer, K. Fostiropoulos, and D. R. Huffman, Chem. Phys. Lett., 96, 4160 (1992)
17 S. H. Kim, J. S. Yoo, J. H. Hahn, and I. C. Jeon, Bull. Kor. Chem. Soc., 14(2), 711(1993)
18 J. C. Lee, T. Y. Kim, S. H. Kang, and Y. K. Shim, Bull. Kor. Chem. Soc., 22(3), 257 (2001)
19 W. Kratschmer, L. D. Lamb, K. Fostiropoulos, and D. R. Huffman, Nature, 347, 354 (1990)   DOI
20 S. H. Glarum, S. J. Duclos, and R. C. Haddon, J. Am. Chem. Soc., 114, 1996 (1992)   DOI