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http://dx.doi.org/10.5229/JKES.2003.6.1.013

A Study on Sol-gel Preparation of Pt-Ru/C Anode Catalysts for Direct Methanol Fuel Cells  

Lee, Kang-Hee (Clean Technology Research Center, Korea Institute of Science and Technology)
Kim, Il-Gon (Clean Technology Research Center, Korea Institute of Science and Technology)
Park, Tae-Jin (Clean Technology Research Center, Korea Institute of Science and Technology)
Suh, Dong-Jin (Clean Technology Research Center, Korea Institute of Science and Technology)
Publication Information
Journal of the Korean Electrochemical Society / v.6, no.1, 2003 , pp. 13-17 More about this Journal
Abstract
Cryogel and aerogel Pt-Ru/C were synthesized by the sol-gel process for the electrooxidation of methanol. From XRD analysis, it was found that the catalysts had highly dispersed Pt-Ru alloys on carbon support although high temperature treatments have been conducted. Electrocatalytic activities of 3 type aerogel catalysts were investigated in half cell experiments by cyclic voltammetry. Among them, Phloroglucinol-Formaldehyde(PF) type catalyst shows the highest activity. From the results of deactivation test for each catalysts, the aerogel catalysts are found to have excellent durability compared with those prepared by colloidal method.
Keywords
Sol-gel method; Aerogel; DMFC; Pt-Ru/C; Catalyst;
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1 /
[ H. A. Gasteiger;N. Makvic;P. N. Ross Jr.;E. J. Cairns ] / J. Phys. Chem.   DOI   ScienceOn
2 /
[ T. Freelink;W. Vischer;A. P. Cox;J. A. R. Van Veen ] / Electrochem. Acta.   DOI   ScienceOn
3 /
[ F. Garin;G. Maire ] / J. Mol. Catal.   DOI   ScienceOn
4 /
[ J. O'M Bockris;H. Wroblowa ] / J. Elctroanal Chem.   DOI   ScienceOn
5 /
[ B. D. McNicol;P. A. Attwood;R. T. Short;J. A. van Amstel ] / J. Chem, Soc. Farad. Trans.   DOI
6 /
[ M. Watanabe;S. Seagust;P. Stonehart ] / J. Elctroanal Chem.   DOI   ScienceOn
7 /
[ J. A. R. Van Veen ] / Electrochim. Acta   DOI   ScienceOn
8 /
[ T. Freelink;W. Vischer ] /
9 /
[ B, J, Kennedy;A. Hammett ] / J. Electroanal Chem.   DOI   ScienceOn
10 /
[ M. Watanabe;M. Uchida;S. Motoo. ] / J. Electroanal Chem.   DOI   ScienceOn
11 /
[ S. A. Campbell;R. Parsons ] / J. Chem. Soc. Farad. Trans.   DOI
12 /
[ H. Miura;R. D. Gonzalez ] / J. Catal.
13 /
[ Y. Takasu;Y. Fujiwara;Y. Murakami;K. Sasaki;M. Oguri;T. Asaki;W. Sugimoto ] / J. Electrochem. Soc.   DOI   ScienceOn
14 /
[ V. Radmilovic;H. A. Gasteiger;P. N. Ross Jr. ] / J. Catal.   DOI
15 /
[ P. Villamil;A. Lopez;R. Gomea ] / React. Kinet. Catal. Lett.   DOI
16 /
[ A. Hamnett ] / Catal. Today   DOI   ScienceOn