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http://dx.doi.org/10.5229/JKES.2002.5.4.189

A Large Trans/cis Conversion Ratio In Redox-Conjugated Single-Light Reversible Isomerization of a Cobalt Complex with meta-Bipyridylazobenzene Ligands  

Kume, Shoko (Department of Chemistry, School of Science, the University)
Kurihara, Masato (Department of Chemistry, School of Science, the University)
Nishihara, Hiroshi (Department of Chemistry, School of Science, the University)
Publication Information
Journal of the Korean Electrochemical Society / v.5, no.4, 2002 , pp. 189-191 More about this Journal
Abstract
Reversible trans-cis isomerization of meta-bipyridylazobenzene coordinated to cobalt was achieved by a combination of photoirradiation with a single UV light source and a Co(II)/Co(III) redox reaction. The trans/cis conversion performance was significantly improved in the meta-form compared with the meta-form ligated to cobalt.
Keywords
Pphotoisomerization; Azobenzene; Cobalt complex; Bipyridine; Redox;
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