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http://dx.doi.org/10.5229/JKES.2002.5.2.079

Application of Monte Carlo Simulation to Intercalation Electrochemistry I. Thermodynamic Approach to Lithium Intercalation into LiMn2O4 Electrode  

Kim, Sung-Woo (Corrosion and Interfacial Electrochemistry Research Laboratory at Department of Materials and Engineering Korea Advanced Institute of Science and Technology)
Pyun, Su-Il (Corrosion and Interfacial Electrochemistry Research Laboratory at Department of Materials and Engineering Korea Advanced Institute of Science and Technology)
Publication Information
Journal of the Korean Electrochemical Society / v.5, no.2, 2002 , pp. 79-85 More about this Journal
Abstract
The present article is concerned with the application of the Monte Carlo simulation to electrochemistry of lithium intercalation from the thermodynamic view point. This article first introduced the fundamental concepts of the ensembles, and Ising and lattice gas models in statistical thermodynamics for the Monte Carlo simulation in brief. Finally the Monte Carlo method based upon the lattice gas model was employed to analyse thermodynamics of the lithium intercalation into the transition metal oxides. Especially we dealt with the thermodynamic properties as the electrode potential curve and the partial molar internal energy and entropy of lithium ion in the case of the $LiMn_2O_4$ electrode, and consequently confirmed the utility of the Monte Carlo method in the field of electrochemistry of the lithium intercalation.
Keywords
Lattice gas model; electrode; Lithium Intercalatioin; Monte Carlo simulation;
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