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http://dx.doi.org/10.17702/jai.2021.22.2.31

Synthesis of Acrylic Nonionic Reactive Emulsifier with Aromatic Ring and the Properties of Water-based Acryl Pressure Sensitive Adhesive  

Yeom, Do-Young (Research Center for Advanced Specialty Chemicals, Korea Research Institute of Chemical Technology)
Kim, Dong Hwan (Research Center for Advanced Specialty Chemicals, Korea Research Institute of Chemical Technology)
Hwang, Gaeun (Research Center for Advanced Specialty Chemicals, Korea Research Institute of Chemical Technology)
Hwang, Do-Hoon (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University)
Jung, Yu Jin (Research Center for Advanced Specialty Chemicals, Korea Research Institute of Chemical Technology)
Publication Information
Journal of Adhesion and Interface / v.22, no.2, 2021 , pp. 31-38 More about this Journal
Abstract
In this study, a nonionic reactive emulsifier with aromatic and acryl group was synthesized by using polyoxyethylene(10) dodecylphenyl ether with 3-butenoic acid. The synthesized nonionic reactive emulsifier was confirmed by 1H-NMR and FT-IR. In addition, the reactive emulsifier synthesized in the preparation of aqueous acrylic adhesives base emulsion was used and the properties of the solid content, conversion, particle size distribution, peel strength and high temperature holding force were compared to those of nonionic emulsifiers without aromatic group. The particle size was distributed from 370 nm to 698 nm, and the peel strength were measured in the range of 1.507~1.802 kgf. The high temperature holding force of prepared adhesives base emulsion were measured in the range of 0.50~2.00 mm. Especially, in the result of synthesized nonionic reactive emulsifier with aromatic group, it was confirmed that high temperature holding force results were the most excellent than the case of using other nonionic reactive emulsifiers, and it can be useful for water-based acryl pressure sensitive adhesive.
Keywords
Nonionic emulsifier; Reactive emulsifier; Adhesive base emulsion; Peel strength; Particle size distribution; High temperature holding force;
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