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http://dx.doi.org/10.17702/jai.2018.19.4.154

Preparation of PDMS Surface Modifier Using Silane-Functionalized Polymer Precursor Manufacture and Their Properties  

Shin, Jae-Hyeon (Department of Materials Engineering, Kangwon National University)
Kim, Nahae (Department of Materials Engineering, Kangwon National University)
Kim, Juyoung (Department of Materials Engineering, Kangwon National University)
Publication Information
Journal of Adhesion and Interface / v.19, no.4, 2018 , pp. 154-162 More about this Journal
Abstract
Plasma treatment and corona treatment have been used for surface modification of polydimethylsiloxane (PDMS) film by activating its surface with the -OH group. Adhesion promoter or coupling agent was also used to improve adhesion of PDMS film with various materials. However, obtained hydrophilicity onto the surface of PDMS films with those processes was transient and vulnerable. In this study, a new alkoxysilane-functionalized acrylic polymer precursor was first synthesized by copolymerization process, and then was reacted with HO-terminated PDMS through condensation reaction to prepare a new surface modifier for PDMS film. The structure and molecular weight of the prepared surface modifier were confirmed by 1H-NMR and GPC measurement. Surface properties of surface modifier-coated PDMS films were also investigated by using XPS, ATR and WCA analysis. The adhesion between the PDMS film and the surface modifier was tested using cross-cut test.
Keywords
$O_2$ plasma treatment; Roll-to-Roll; PDMS Surface treatment; Acrylic copolymer; Surface modifier;
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1 N.E Stankova, P.A Atanasov, Ru.G. Nikov, R.G. Nikov, et al., Appl. Surf. Sci., 374, 96-103 (2016).   DOI
2 Y. H. Kim, M. G. Jeong, H. O. Seo, et al. Appl. Surf. Sci., 258, 7562-7566 (2012).   DOI
3 J. M K. Ng, I. Gitlin, A. D. Stroock, G. M. Whitesides, Electrophoresis, 23, 3461-3473 (2002).   DOI
4 E. P. Kartalob, W. F. Anderson, A. Schere, Journal of Nanoscience and Nanotechnology, 6, 2265-2277 (2006).   DOI
5 D.M. Smith, R. G. Lehmann, R. Narayan, G.E Kozerski, Compost Science & Untilization, 6, 6-12 (1998).
6 Li K, Zeng X, Li H, Colloids Surf., A : Physic. Eng. Asp., 445, 111-118 (2014).   DOI
7 Z. Yuan, J. Bin, X. Wang, Surf. Coat. Technol., 254, 97-103(2014).   DOI
8 S. Pinto, P. Alves, C.M. Matos, Colloid Surf. B: Biointerf., 81, 20-26(2010).   DOI
9 S. Wu. Surface and interfacial tensions of polymers, oligomers, plasticizers, and organic pigments, Polymer handbook (Eds J. Brandup, E. H. Immergut, E. A Grulke, A. Abe, D. R. Bloch, Wiley, New York), 1989.
10 B. Schnyder, T. Lippert, R. Kotz, A. Wokaun, V.M Graubner, O.Nuyken, Surf. Sci., 1067, (2003).
11 J. Kim, M.K Chaudhury, M.J Owen, J. Colloid Interface Sci., 226, 231-236 (2000).   DOI
12 K. Kim, S. W Park, S.S. Yang, BioChip Journal, 4, 148-154 (2010).   DOI
13 C. W. Beh, W. Zhou, T. Wang, Lab Ship, 12, 4120-4127(2012).
14 S. H. Tan, N. Nguyen, Y. C. Chua, Biomicrofluidics, 4, 032204-1-032204-8, (2010).   DOI
15 Z. Almutairi, C. L. Ren, L. Simon, Colloids Surf., A : Physic. Eng. Asp., 415, 406-412(2012).   DOI
16 C. Cheng, K.T. Powell, E. Koshdel, K. L. Wooley, Macromol., 40, 7195-7207 (2007).   DOI
17 H. Samu, V. Juan V. C. Rodriguez, J. Kreutzer, Appl. Surf. Sci., 258, 9864-9875 (2012).   DOI
18 H. T. Kim, O. C. Jeong, Microelectron. Eng., 88, 2281-2285 (2011).   DOI
19 L. A. Bloomfield, Journal of adhesion & adhesive, 68, 239-237 (2016).   DOI
20 S.C. Debora, C. V. Eliane, A. Galembeck, Polym. Eng. Sci., 50, 606-612 (2010).   DOI
21 Ying Ma, Xinyu Cao, Xinjian Feng, Yongmei Ma, Hong Zou, Polymer, 48, 7455-7460 (2007).   DOI