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http://dx.doi.org/10.17702/jai.2014.15.3.093

Part 1 : Soap-Free Emulsion Copolymerization of Styrene with COPS-I  

Lee, KiChang (Department of Polymer Science and Engineering, School of Nano and Advanced Materials, Engineering Research Institute, Gyeongsang National University)
Choo, HunSeung (Department of Polymer Science and Engineering, School of Nano and Advanced Materials, Engineering Research Institute, Gyeongsang National University)
Ha, JeongMi (Department of Polymer Science and Engineering, School of Nano and Advanced Materials, Engineering Research Institute, Gyeongsang National University)
Publication Information
Journal of Adhesion and Interface / v.15, no.3, 2014 , pp. 93-99 More about this Journal
Abstract
Monodisperse poly[styrene-co-(COPS-I)] latices in the size range of 165~550nm were successfully prepared by soap-free emulsion polymerization with various polymerization conditions (Styrene, COPS-I, KPS, DVB concentrations and polymerization temperature). In general, the COPS-I and KPS, DVB concentrations and polymerization temperature were closely related to the polymerization rate and the number of particles, molecular weight, and zeta potential. The polymerization rate and zeta potential increased, but molecular weight decreased, with increasing in the number of particles.
Keywords
surfactant-free emulsion copolymerization; styrene; sodium 1-allyloxy-2-hydroxypropane sulfonate (COPS-I); the number of particles and molecular weight; polymerization rate;
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