Browse > Article

Preparation and Properties of UV Curable Phlorogulcinol Based Acrylate for PET Film  

Choi, Jeon-Mo (Green chemistry & Manufacturing System Division Team, Korea Institute of Industrial Technology (KITECH))
Lee, Eun-Young (Green chemistry & Manufacturing System Division Team, Korea Institute of Industrial Technology (KITECH))
Kim, Sangyong (Green chemistry & Manufacturing System Division Team, Korea Institute of Industrial Technology (KITECH))
Cho, Jin-Ku (Green chemistry & Manufacturing System Division Team, Korea Institute of Industrial Technology (KITECH))
Kim, Baekjin (Green chemistry & Manufacturing System Division Team, Korea Institute of Industrial Technology (KITECH))
Lee, Sang-Hyeup (Department of Life Chemistry, Catholic University of Daegu)
Kim, Hyun Joong (Lab. of Adhesion & Bio-Composites, Program in Environmental Materials, Research Team for Biomass-based Bio-Materials, Seoul National University)
Publication Information
Journal of Adhesion and Interface / v.11, no.2, 2010 , pp. 50-56 More about this Journal
Abstract
Polyethyleneterephthalate (PET) film is widely used in various industrial fields such as mobile phone, display pannel, notebook etc. Recently PET film attached on indium tin oxide (ITO) surface has a role of high pencil hardness, high refractive index etc. So we synthesized two types of multi-functional monomer which are epoxy modifed acrylate and unmodified acrylate type using recyclable resource like phloroglucinol, derived from trinitrotoluene. We studied the effect of multi-functional monomer's chemical structure on the various properties such as refractive index, optical transmittance, and pencil hardness. We characterized synthesized multi-functional monomer by qualitative analysis through H NMR. We observed that pencil hardness of 1,3,5-triepoxide benzene and 1,3,5-triacrylate benzene they have the range of 2~3 H at high UV dosage of 300 mW. Refractive index appeared the value of 1.54~1.57. Transmittance of all multi-functional monomers has more than 93%.
Keywords
Phloroglucinol based acrylate; UV; PET film; hardcoating; functionality;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 M. Braithwaite, "Chemistry & Technology of UV & EB Formulation for Coatings, Inks & Paints", SITA Technology, London (1991).
2 S. P. Pappas, "Radiation Curing", Plenum Press, New York (1992).
3 J. M. Cheon, B. Y. Jeong, S. T. Oh, T. K. Kim, and J. H. Chun, Adhesion and Interface, 11, 35 (2010).
4 T. Doba, Journal of adhesion society of Japan, 35, 521 (1999).
5 S. J. Jeon, W. Kim, J. J. Lee, and S. M. Koo, J. of Korean Ind. & Eng. Chemistry, 17, 580 (2006).
6 Y. C. Kim and B. H. Lee, Adhesion and Interface, 10, 191 (2009).
7 Y. S. Lee, E. S. Lee, and J. K. Ha, Adhesion and Interface, 11, 9 (2010).
8 M. J. Moon, J. H. Park, G. D. Lee, C. S. Suh, and J. R. Kim, J. Korean Ind. Eng. Chem., 2, 175 (1991).
9 R. Mehnert, A. Pincus, I. Jnorsky, R. Stowe, A. berejka, "UV & EB Curing Technology & Equipment", John Wiley & Sons, New York (1998).
10 M. Ghaemy, S. Bekhradnia, and M. Heidaripour, J. Appl. Polym. Sci., 110, 983 (2008).   DOI   ScienceOn
11 S. Lee and S. H. Jin, J. of the Korean Oil Chemists' Soc., 26, 467 (2009).   과학기술학회마을
12 S. Zollner, Proceedings radtech Europe, 99, 591 (1999).
13 R. Muller, Proceedings radtech Europe, 99, 591 (1999).
14 H. S. Do, Y. J. Park, S. Kim, D. H. Lim, and H. J. Kim, Prospect. Ind. Chem., 7, 14 (2004).
15 B. S. Park, Theor. Appl. Chem. Eng., 12, 1201 (2006).
16 A. R. Mitchell, M. D. Coburn, R. D. Schmidt, P. F. Pagoria, and G. S. Lee, Thermochim. Acta, 384, 205 (2002).   DOI
17 W. H. Lee, J. S. Kim, and S. C. Kim, Bull. Korean Chem. Soc., 30, 3105 (2009).   DOI