Browse > Article
http://dx.doi.org/10.5012/jkcs.2020.64.4.203

Speciation Analysis of Seleno-Compounds in Hair and Finger Nails  

Ji, Young (Department of Chemistry Education, Korea National University of Education)
Keum, Daeseop (Department of Chemistry Education, Korea National University of Education)
Pak, Yong N. (Department of Chemistry Education, Korea National University of Education)
Publication Information
Journal of the Korean Chemical Society / v.64, no.4, 2020 , pp. 203-209 More about this Journal
Abstract
Selenium species in hair and nails were extracted, separated and analyzed with HPLC-ICP/MS. The result showed that Se species was mostly SeCys and the information related to the change of selenium concentration in a body could be obtained. The Se fortification study was performed for 5 participants during 12 months. The average of Se concentration was 858.6 ± 201.2 ng g-1, which did not change much during the research period nor the difference between the individuals was striking. In the case of hair, the average concentration was 205.3 ng g-1 which was lower than nails. Se supplement of 22 ㎍ day-1 was taken for 3 months by the volunteers and the difference between before and after (3 months period for each) the taking of supplement was not striking. However, when the dose was increased to 300 ㎍ day-1 for 2 months, the concentration was increased noticeably to 1,230 ng g-1. It can be thought that the analysis of finger nail for Se can provide valuable information for the long period (several months) of exposure or intake of Se for a human body.
Keywords
Selenium speciation; Selenium-fortified Spirulina; Isotope dilution; HPLC-ICP/MS;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Chung, A. S.; Park, J. M.; Kim, A. Journal of Korean Association 2004, 9, 8.
2 Kumar, B. S.; Priyadarsini, K. I. Biomedicine & Preventive Nutrition 2014, 4, 333.   DOI
3 Tapiero, H.; Townsend, D. M.; Tew, K. D. Biomedicine &pharmacotherapy 2003, 57, 134.   DOI
4 Deagen, J. T.; Beilstein, M. A.; Whanger, P. D. Journal of inorganic biochemistry 1991, 41, 261.   DOI
5 Nuttall, K. L. Annals of Clinical &Laboratory Science 2006, 36, 409
6 Navarro-Alarcon, M.; Cabrera-Vique, C. Science of the total environment 2008, 400, 115.   DOI
7 Ashton, K.; Hooper, L.; Harvey, L. J.; Hurst, R.; Casgrain, A.; Fairweather-Tait, S. J. The American journal of clinical nutrition 2009, 89, 2025S.   DOI
8 Vinceti, M.; Filippini, T.; Cilloni, S.; Crespi, C. M. Advances in cancer research 2017, 136, pp. 1-48 Academic Press.   DOI
9 Reyes, L. H.; Gayon, J. M.; Alonso, J. G.; Sanz-Medel, A. Journal of Analytical Atomic Spectrometry 2003, 18, 11.   DOI
10 Zhu, Y. S.; Xu, H. B.; Huang, K. X.; Hu, W. H.; Liu, M. L. Biological trace element research 2002, 89, 155.   DOI
11 Navarro-Alarcon, M.; de la Serrana, H. L. G.; Perez-Valero, V.; Lopez-Marti'nez, C. Science of the total environment 1999, 228, 79.   DOI
12 Longnecker, M. P.; Stampfer, M. J.; Morris, J. S.; Spate, V.; Baskett, C.; Mason, M.; Willett, W. C. The American journal of clinical nutrition 1993, 57, 408.   DOI
13 Kaluza. J., Jeruszka, M and Brzozowska, A. Roczniki Panstwowego Zakadu Higieny. 2001, 52, 111.
14 D'Ilos, S.; Violante, N.; Senefonte, O. Microchemical Journal 2000, 67, 343.   DOI
15 Rashed. M. N.; Hossam, F., Environmental Bioindicators 2007, 2, 131.   DOI
16 Rahman, L.; Corns, W. T.; Bryce, D. W.; Stockwell, P. B. Talanta 2000, 52, 833.   DOI
17 Liu, Y.; Hu, Z.; Gao, S.; Gunther, D.; Xu, J.; Gao, C.; Chen, H. Chemical Geology 2008, 257, 34.   DOI
18 He, K. Eur. J. Clin. Invest. 2011, 41, 98.   DOI
19 Diskin, C. J.; Tomasso, C. L.; Alper, J. C.; Glaser, M. L.; Fliegel, S. E. Archives of Internal Medicine 1979, 139, 824.   DOI
20 Allen, N. E.; Travis, R.; Appleby, P.; Albanes, D.; Barnett, M.; Black, A.; Bueno-de-Mesquita, H.; Deschasaux, M.; Galan, P.; Goodman, G.; Goodman, P.; Gunter, M.; Heliovaara, M.; Helzlsouer, K.; Henderson, B.; Hercberg, S.; Knekt, P.; Kolonel, L.; Lasheras, C.; Linseisen, J.; Metter, E.; Neuhouser, M.; Olsen, A.; Pala, V.; Platz, E.; Rissanen, H.; Reid, M.; Schenk, J.; Stampfer, M.; Stattin, P.; Tangen, C.; Touvier, M.; Trichopoulou, A.; van den Brandt, P.; Key, T. Journal of the National Cancer Institute 2016, 108, 153.   DOI
21 Fleming, D. E.; Nader, M. N.; Foran, K. A.; Groskopf, C.; Reno, M. C.; Ware, C. S.; Tehrani, M.; Guimaraes, D.; Parsons, P. J. Appl. Radiat. Isot. 2017, 120, 1.   DOI
22 Jenner, F. E.; Holden, P.; Mavrogenes, J. A.; O'Neill, H. S. C.; Allen, C. Geostandards and Geoanalytical Research 2009, 33, 309.   DOI
23 Alonso, J. G. Analytica chimica acta 1995, 312, 57.   DOI
24 Rodriguez-Gonzalez, P.; Marchante-Gayon, J. M.; Alonso, J. I. G.; Sanz-Medel, A. Spectrochimica Acta B 2005, 60, 151.   DOI
25 Gine, M. F.; Packer, A. P. Journal of the Brazilian Chemical Society 2010, 21, 575.   DOI
26 Xia, Y.; Ha, P.; Hill, K.; Butler, J.; Whanger, P. The Journal of Trace Elements in Experimental Medicine 2000, 13, 333.   DOI
27 Choi, M. K.; Kank, M. H.; Kim, M. H. Biol. Trace Elem. Res. 2009, 128, 104.   DOI