Browse > Article
http://dx.doi.org/10.5012/jkcs.2019.63.3.160

Reaction and Theoretical Study of the Coordination of an N2O-Donor Amino Alcoholic Ligand Toward Group 12 Metals Mixtures  

Mardani, Zahra (Inorganic Chemistry Department, Faculty of Chemistry, Urmia University)
Moeini, Keyvan (Chemistry Department, Payame Noor University)
Kazemshoar-Duzduzani, Reza (Inorganic Chemistry Department, Faculty of Chemistry, Urmia University)
Publication Information
Journal of the Korean Chemical Society / v.63, no.3, 2019 , pp. 160-165 More about this Journal
Abstract
A series of reactions between an amino alcoholic ligand, cis-2-((2-((2-hydroxyethyl)amino)ethyl)amino)cyclohexan-1-ol (HEAC), with the mixtures of group 12 metals including, $HgCl_2/CdCl_2$, $HgCl_2/CdI_2$, $ZnCl_2/CdCl_2$ and $ZnCl_2/CdCl_2/HgCl_2$ was experimentally and theoretically studied to determine the most stable product of these reactions. Furthermore, the Cambridge Structural Database (CSD) studies were done to evaluate the theoretical results. The products were characterized by elemental analysis, FT-IR, Raman, $^1H$ NMR spectroscopy and single-crystal X-ray diffraction. Based on these investigations a binuclear structure of cadmium, [$Cd_2(HEAC)_2({\mu}-Cl)_2Cl_2$] (1), is the most stable product that was formed in all studied reactions between HEAC and metals mixtures. In this structure, the cadmium atom has a $CdN_2O({\mu}-Cl)_2Cl$ environment and distorted octahedral geometry.
Keywords
Cadmium; Group 12; Amino alcohol; Metal mixture; DFT study;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Allen, F. H. Acta Crystallogr. 2002, B58, 380.   DOI
2 Tang, X.-Y.; Yu, H.; Gao, B.-B.; Lang, J.-P. Dalton Trans. 2017, 46, 14724.   DOI
3 He, J.; Zha, M.; Cui, J.; Zeller, M.; Hunter, A. D.; Yiu, S.-M.; Lee, S.-T.; Xu, Z. J. Am. Chem. Soc. 2013, 135, 7807.   DOI
4 Park, I.-H.; Kim, J.-Y.; Kim, K.; Lee, S. S. Cryst. Growth Des. 2014, 14, 6012.   DOI
5 Li, S.-L.; Wu, J.-Y.; Tian, Y.-P.; Ming, H.; Wang, P.; Jiang, M.-H.; Fun, H.-K. Eur. J. Inorg. Chem. 2006, 14, 2900.
6 Wang, X.-Q.; Yu, W.-T.; Hou, X.-Q.; Xu, D.; Geng, Y.-L. Acta Crystallogr. 2006, E62, m2333.
7 Wang, X. Q.; Yu, W. T.; Xu, D.; Zhang, G. H. Acta Crystallogr. 2005, E61, m1147.
8 Wang, X. Q.; Yu, W. T.; Xu, D.; Sun, H. Q. Acta Crystallogr. 2005, E61, m548.
9 Chen, W.-T.; Zeng, X.-R.; Liu, D.-S.; Ying, S.-M.; Liu, J.-H. Chin. J. Chem. 2008, 26, 1678.   DOI
10 Liu, X.; Wang, X.; Yin, X.; Zhang, S.; Wang, L.; Zhu, L.; Zhang, G.; Xu, D. J. Mater. Chem. C 2014, 2, 723.   DOI
11 Hallinger, M. R.; Gerhard, A. C.; Ritz, M. D.; Sacks, J. S.; Poutsma, J. C.; Pike, R. D.; Wojtas, L.; Bebout, D. C. ACS Omega 2017, 2, 6391.   DOI
12 Wang, H.; Zhang, D.; Ni, Z.-H.; Li, X.; Tian, L.; Jiang, J. Inorg. Chem. 2009, 48, 5946.   DOI
13 Wang, Y.; Bredenkotter, B.; Rieger, B.; Volkmer, D. Dalton Trans. 2007, 689.   DOI
14 Hakimi, M.; Mardani, Z.; Moeini, K.; Mohr, F.; Fernandes, M. A. Polyhedron 2014, 67, 27.   DOI
15 Hakimi, M.; Mardani, Z.; Moeini, K.; Fernandes, M. A. J. Coord. Chem. 2012, 65, 2221.   DOI
16 Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H. J. Appl. Crystallogr. 2009, 42, 339.   DOI
17 Marandi, F.; Amoopour, F.; Pantenburg, I.; Meyer, G. J. Mol. Struct. 2010, 973, 124.   DOI
18 Marandi, F.; Moeini, K.; Alizadeh, F.; Mardani, Z.; Quah, C. K.; Loh, W.-S.; Woollins, J. D. Inorg. Chim. Acta 2018, 482, 717.   DOI
19 Marandi, F.; Moeini, K.; Arkak, A.; Mardani, Z.; Krautscheid, H. J. Coord. Chem. 2018, Accepted.
20 Farrugia, L. J. J. Appl. Crystallogr. 1997, 30, 565.   DOI
21 Burnett, M. N.; Johnson, C. K., Ortep-III, Report ORNL-6895. Oak Ridge National Laboratory, Oak Ridge, Tennessee, U.S.: 1996.
22 Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Mennucci, B.; Petersson, G. A.; Nakatsuji, H.; Caricato, M.; Li, X.; Hratchian, H. P.; Izmaylov, A. F.; Bloino, J.; Zheng, G.; Sonnenberg, J. L.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Vreven, T.; Montgomery Jr., J. A.; Peralta, J. E.; Ogliaro, F.; Bearpark, M. J.; Heyd, J.; Brothers, E. N.; Kudin, K. N.; Staroverov, V. N.; Kobayashi, R.; Normand, J.; Raghavachari, K.; Rendell, A. P.; Burant, J. C.; Iyengar, S. S.; Tomasi, J.; Cossi, M.; Rega, N.; Millam, N. J.; Klene, M.; Knox, J. E.; Cross, J. B.; Bakken, V.; Adamo, C.; Jaramillo, J.; Gomperts, R.; Stratmann, R. E.; Yazyev, O.; Austin, A. J.; Cammi, R.; Pomelli, C.; Ochterski, J. W.; Martin, R. L.; Morokuma, K.; Zakrzewski, V. G.; Voth, G. A.; Salvador, P.; Dannenberg, J. J.; Dapprich, S.; Daniels, A. D.; Farkas, O.; Foresman, J. B.; Ortiz, J. V.; Cioslowski, J.; Fox, D. J. Gaussian 09, Gaussian, Inc.: Wallingford, CT, USA, 2009.
23 Perdew, J. P. Phys. Rev. B 1986, 33, 8822.   DOI
24 Becke, A. D. J. Chem. Phys. 1993, 98, 5648.   DOI
25 Ditchfield, R.; Hehre, W. J.; Pople, J. A. J. Chem. Phys. 1971, 54, 724.   DOI
26 Vittal, J. J.; Dean, P. A. W. Polyhedron 1998, 17, 1937.   DOI
27 Hay, P. J.; Wadt, W. R. J. Chem. Phys. 1985, 82, 270.   DOI
28 Nakamoto, K. In Infrared and Raman Spectra of Inorganic and Coordination Compounds, 6 ed.; John Wiley & Sons, Inc, Hoboken: 2009; p 324.