Browse > Article
http://dx.doi.org/10.5012/jkcs.2017.61.4.191

Preparation and Characterization of Thiolate-Protected Gold Nanoparticles Using Modified One-Phase Method  

Park, Jisu (Department of Chemistry, College of Natural Sciences, Dankook University)
Kim, Youhyuk (Department of Chemistry, College of Natural Sciences, Dankook University)
Publication Information
Journal of the Korean Chemical Society / v.61, no.4, 2017 , pp. 191-196 More about this Journal
Abstract
One-phase method to prevent the initial formation of Ag(I) thiolate layered materal from the mixture of $AgNO_3$ and thiols was previously developed to generate TP (Thiolate-Protected)-nanosilver. In this modified method, $AgNO_3$ is added to the mixtures of $NaBH_4$ and thiols in ethanol. This method was so successful that it was applied to synthesize TP-nanogold and nanoplatinum. The synthesis and characterization of these nanoparticles by ultraviolet-visible (UV-vis) absorption spectra, transmission electron microscopy (TEM) pictures, X-ray powder differaction (XRD) patterns and infrared(IR) spectra are described. The results show that colloidal nanoparticles are spherical or oval shape and the mean sizes for TP-nanogold and nanoplatinum are about 3~7 nm and below 2 nm, respectively. The conformation of polymethylene [$-(CH_2)_7-$] sequence in octanethiolate attached to nanogold was elucidated as trans.
Keywords
TP(Thiolate-Protected)-; Nanoparticles; One phase synthetic method; Conformation of polymethylene;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Sun, S. H., Murray, C. B., Weller, D., Folks, L.; Moser, A. Science 2000, 287, 1989.   DOI
2 Sun, Y. G.; Xia, Y. N. Science 2002, 298, 2176.   DOI
3 Amato, E.; Diaz-Fernandez, Y. A.; Taglietti, A.; Pallavicini, P.; Pasotti, L.; Cucca, L.; Milanese, C.; Grisoli, P.; Dacarro, C.; Fernandez-Hechavarria, J. M.; Necchi, V. Langmuir 2011, 27, 9165.   DOI
4 Mirkin, C. A.; Letsinger, R. L.; Mucic, R. C.; Storhoff, J. J. Nature 1996, 382, 607.   DOI
5 Manz, C.; Williams, L.; Mohseni, R.; Zlotnikov, E.; Vasiliev, A. Colloids and Surfaces A Physicochem. Eng. Aspects 2011, 385, 201.   DOI
6 Chia, C.; Shinn, J. C.; Fan, J. S.;, Shu, W. L.; Yi, C. C. Colloids and Surfaces A: Physicochem. Eng. Aspects 2013, 419, 209.   DOI
7 Aslam, A.; Lei Fu, L.; Su, M.; Vijayamohan, K.; Dravid, V. P. J. Mater. Chem., 2004, 14, 1795.   DOI
8 Liu, J.; Lee, J. B.; Kim, D. H.; Kim, Y. Colloids and Surfaces A: Physicochem. Eng. Aspects 2007, 302, 276.   DOI
9 Brust, M.; Walker, M.; Bethell, D.; Schiffrin, D. J.; Whyman, R. J. Chem. Soc., Chem. Commun. 1994, 7, 801.
10 Mari, A.; Imperatori, P.; Marchegiani, G.; Pilloni, L.; Mezzi, A.; Kaciulis, S.; Cannas, C.; Meneghini, C.; Mobilio, S.; Suber, L. Langmuir 2010, 26, 15561.   DOI
11 Brust, M.; Fink, J.; Bethell, D.; Schiffrin, J.; Kiely, C. J. Chem. Soc., Chem. Commun. 1995, 16, 1655.
12 Sarathy, K. V.; Raina, G.; Yadav, R. T.; Kulkarni, G. U.; Rao, C. N. R. J. Phys. Chem. B 1997, 101, 9876.   DOI
13 Kang, S. Y.; Kim, K. Langmuir 1998, 14, 226.   DOI
14 Goulet, P. J. G.; Lennox, R. B. J. Am. Chem. Soc. 2010, 132, 9582.   DOI
15 Jeong M. H.; Hong, J. Y.; Park, J. S.; Kim, Y. Bull. Korean Chem. Soc. 2016, 37, 736.   DOI
16 Liz-Marza, L. M. Langmuir 2006, 22, 32.   DOI
17 He, S.; Yao, J.; Jiang, P.; Shi, D.; Zhang, H.; Xie, S.; Pang, S.; Gao, H. Langmuir 2001, 17, 1571.   DOI
18 Yee, C.; Scotti, M.; Ulman, A.; White, H.; Rafailovich, M.; Sokolov, J. Langmuir 1999, 15, 4314.   DOI
19 Rao, C. N. R.; Vijayakrishnan, V.; Aiyer, H. N.; Kulkarni, G. U.; Subbanna, G. N. J. Phys. Chem. 1993, 97, 11157.   DOI
20 Patterson A. L. Phys. Rev. 1939, 56, 978.   DOI
21 Parikh, A. N.; Gillmor, S. D.; Beers, J. D.; Beardmore, K. M.; Cutts, R. W.; Swanson, B. I. J. Phys. Chem. B 1999, 103, 2850.   DOI
22 MacPhail, R. A.; Strauss, H. L.; Snyder, R. G.; Elliger, C. A. J. Phys. Chem. 1982, 88, 334.