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http://dx.doi.org/10.5012/jkcs.2016.60.1.28

A Study on the Photo-Degradation Properties of the Spiropyran Using THz-TDS  

Bang, Jin-Hyuk (Department of Convergence Science, Sahmyook University)
Park, Myoung-Hwan (Department of Convergence Science, Sahmyook University)
Ryu, Han-Cheol (Department of Convergence Science, Sahmyook University)
Publication Information
Journal of the Korean Chemical Society / v.60, no.1, 2016 , pp. 28-33 More about this Journal
Abstract
The spiropyran is a typical material having photodegradation properties in the process of photochromism. The spiropyran has been utilized in various applications such as optical switch, optical memories, and biosensor because of its remarkable stability, fast responsive time, stronger color change, and photo-induced controllability. However, the spriropyran is photodegraded by the repetitive optical irradiation. The photodegradation of spiropyran have been investigated by using UV-Visible spectroscopy, nuclear magnetic resonance (NMR), and Raman spectroscopy. Herein, the properties of spiropyran were characterized by using terahertz time-domain spectroscopy (THz-TDS) in the terahertz frequency region. In terahertz region, the measured absorbance of spiropyran was increased due to the photodegradation induced by the repetitive UV irradiation. The absorbance tendency of spiropyran in the terahertz frequency region was compared with that in the visible region, and they were completely opposite to each other.
Keywords
THz-TDS; Spiropyran; Photodegradation;
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