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http://dx.doi.org/10.5012/jkcs.2015.59.3.225

Simultaneous Determination of Ultra-Trace Pesticides and Synthetic Materials in Surface Water by LC-ESI-MS/MS  

Hong, Seon-Haw (Geum River Environment Research Center, National Institute of Environmental Research)
Lee, Jun-Bae (Geum River Environment Research Center, National Institute of Environmental Research)
Lee, Soo-Hyung (Geum River Environment Research Center, National Institute of Environmental Research)
Cho, Young-Hwan (Department of Environmental Science, Kongju National University)
Shin, Ho-Sang (Department of Environmental Education, Kongju National University)
Publication Information
Journal of the Korean Chemical Society / v.59, no.3, 2015 , pp. 225-232 More about this Journal
Abstract
A liquid chromatography-electrospray ionization-tandem mass spectrometry method (LC-ESI-MS/MS) was used for determining seven pesticides (2,4-dichlorophenoxyacetic acid, methomyl, aldicarb, 2-methyl- 4-chlorophenoxy- acetic acid, molinate, carbaryl and carbofuran) and two synthetic materials (quinoline and bisphenol-A) in surface water. The analytes were extracted using solid-phase extraction (SPE). The eluate was concentrated by nitrogen gas. 100 microliters of 30% (v/v) methanol aqueous solution were used to dissolve the residue and an aliquot of the reconstituted solution was directly injected into LC-ESI-MS/MS after the filtration using 0.2 μm polytetrafluoroethylene (PTFE) syringe filter. Under the established condition, the calibration curves of the analytes were linear with correlation coefficients of above 0.997. The quantification limit was 0.002~0.011 μg/L and the relative standard deviations were less than 16.4%. In addition, accuracy was in the range of 84~107% and the recoveries were values between 56.2 and 98.6%. In this study, the developed method was applied to the analysis of real surface water samples.
Keywords
Pesticide; Synthetic material; Surface water; Solid phase extraction; Liquid chromatography-tandem mass spectrometry;
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  • Reference
1 IARC, Monographs Supplement 7 1987 (http://monographs.iarc.fr/ENG/Monographs/suppl7/Suppl7-48.pdf).
2 US EPA, Reregistration Eligiblility Decision for Methomyl 1998 (http://www.epa.gov/pesticides/reregistration/REDs/0028red.pdf).
3 US EPA, Reregistration Eligiblility Decision for Aldicarb 2007 (http://www.epa.gov/pesticides/reregistration/REDs/aldicarb_red.pdf).
4 US EPA, Illegal Pesticide Products 2012 (http://www.epa.gov/pesticides/health/illegalproducts/#pet).
5 Tankiewicz, M.; Morrison b, C.; Biziuk, M. Talanta 2013, 107, 1.   DOI
6 Quintana, J.; Martí, I.; Ventura, F. J. Chromatogr. A 2001, 938, 3.   DOI
7 Filho, A. M.; Santos, F. N.; Pereira, P. A. P. Microchem. J. 2010, 96, 139.   DOI
8 Shi, Z.; Hu, J.; Li, Q.; Zhang, S.; Liang, Y.; Zhang, H. J. Chromatogr. A 2014, 1355, 219.   DOI
9 Xu, C.; Armstrong, D. W. Analytica Chimica Acta 2013, 792, 1.   DOI
10 Reemtsma, T.; Alder, L.; Banasiak, U. J. Chromatogr. A 2013, 1271, 95.   DOI
11 Korean Crop Protection Association. Annual Report of the Pesticides; Korean Crop Protection Association: Seoul, Korea, 2012.
12 Kwon, Y. J.; Kang, T. S.; Kim, K. R.; Lee, K. S.; Ju, Y. S.; Song, J. C. Korean J. of Rural Med. 2004, 29(2), 265.
13 US EPA, Reregistration Eligiblility Decision for 2,4-D 2005(http://www.epa.gov/pesticides/reregistration/ REDs/ 24d_red.pdf).
14 US EPA, Method 1699 2007 (http://water.epa.gov/scitech/methods/cwa/bioindicators/upload/2008_01_03_methods_-method_1699.pdf).
15 Dong, C.; Zeng, Z.; Yang, M. Wat. Res. 2005, 39, 4204.   DOI
16 Llasera, M. P. G.; Lez, M. B. Wat. Res. 2001, 35(8), 1933.   DOI
17 Subhani, Q.; Huang, Z. P.; Zhu, Z. Y.; Liu, L. Y.; Zhu, Y. Chin. Chem. Lett. 2014, 25, 415.   DOI
18 USDA, EXTOXNET (Extension Toxicology Network) 1993 (http://pmep.cce.cornell.edu/profiles/extoxnet/haloxyfopmethylparathion/mcpa-ext.html#6).
19 US EPA, Method 508.1 1995 (http://water.epa.gov/scitech/methods/cwa/bioindicators/upload/2007_11_06_methods_method_508_1-2.pdf).
20 US EPA, Method 507 1989 (http://water.epa.gov/scitech/methods/cwa/bioindicators/upload/2007_11_06_methods_method_507.pdf).
21 USDA, EXTOXNET (Extension Toxicology Network) 1996 (http://extoxnet.orst.edu/pips/molinate.htm).
22 NPIC, Carbaryl(General Fact Sheet) 2003 (http://npic.orst.edu/factsheets/carbgen.pdf).
23 US EPA, Quinoline-Hazard summary 2000 (http://www.epa.gov/airtoxics/hlthef/quinolin.html#ref4).
24 Korea Food and Drug Administration. Hazardous material series; Korea Food and Drug Administration: Osong, Korea, 2010.
25 Giordano, A.; Richter, P.; Ahumada, I. Talanta 2011, 85, 2425.   DOI
26 Bonansea, R. I.; Ame, M. V.; Wunderlin, D. A. Chemosphere 2013, 90, 1860.   DOI
27 Pinheiro, A. S.; Rocha, G. O.; Andrade, J. B. Microchem. J. 2011, 99, 303.   DOI
28 Corcia, A. D.; Nazzari, M., Rao, R.; Samperi, R.; Sebastiani, E. J. Chromatogr. A 2000, 878, 87.   DOI
29 Gervais, G.; Brosillon, S.; Laplanche, A.; Helen, C. J. Chromatogr. A 2008, 1202, 163.   DOI
30 Dujaković, N.; Grujić, S.; Radišić, M.; Vasiljević, T.; Laušević, M. Analytica Chimica Acta 2010, 678, 63.   DOI
31 Boussahel, R.; Bouland, S.; Moussaoui, K. M.; Baudu, M.; Montiel, A. Wat. Res. 2002, 36, 1909.   DOI
32 Farajzadeh, M. A.; Khoshmaram, L. Food. Chem. 2013, 141, 1881.   DOI
33 Xiong, J.; Hu, B. J. Chromatogr. A 2008, 1193, 7.   DOI
34 Su, Y. S.; Jen, J. F. J. Chromatogr. A 2010, 1217, 5043.   DOI
35 Korean Crop Protection Association. Pesticide Guide; Korean Crop Protection Association: Seoul, Korea, 2012.
36 Assoumani, A.; Margoum, C.; Chataing, S.; Guillemain, C.; Coquery, M. J. Chromatogr. A 2014, 1333, 1.   DOI