Browse > Article
http://dx.doi.org/10.5012/jkcs.2014.58.3.258

Crystal Growth, Spectral, Magnetic, Antibacterial and Antifungal Studies of Co(II) and Ni(II) Complexes of 4-Nitrobenzoic Acid  

Roy, Sunalya M. (Department of Chemistry, Mahatma Gandhi College)
Sudarsanakumar, M.R. (Department of Chemistry, Mahatma Gandhi College)
Dhanya, V.S. (Department of Chemistry, Mahatma Gandhi College)
Suma, S. (Department of Chemistry, Sree Narayana College, Chempazhanthy)
Kurup, M.R. Prathapachandra (Department of Applied Chemistry, Cochin University of Science and Technology)
Publication Information
Journal of the Korean Chemical Society / v.58, no.3, 2014 , pp. 258-266 More about this Journal
Abstract
Single crystals of cobalt(II) and nickel(II) complexes of 4-nitrobenzoic acid have been successfully grown by gel diffusion technique. The grown crystals were characterized by elemental analysis, FT-IR and UV-Visible spectroscopy. The structure of the grown crystals was elucidated using single crystal X-ray diffraction studies. The title compounds $[Co(Pnba)_2(H_2O)_4]{\cdot}2H_2O$ 1 and $[Ni(Pnba)_2(H_2O)_4]{\cdot}2H_2O$ 2 where PnbaH=4-nitrobenzoic acid, crystallize in centrosymmetric triclinic space group P-1. Magnetic susceptibility measurements reveal that the compounds are paramagnetic in nature. The mechanical strength of the grown crystals was determined by Vicker's microhardness studies. The ligand (4-nitrobenzoic acid) and the complexes have been screened for their biological activity against various bacteria and fungi. The activity data show that the biological activity of the complexes is higher than that of the ligand.
Keywords
Gel diffusion; X-ray diffraction; IR spectra; Microhardness; Biological activity;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 Aly, M. A. Hassan, J. Islamic Acad. Sci. 1991, 4, 271.
2 Cotton F. A., Wilkinson G. Advanced Inorganic Chemistry; Wiley Interscience: New York, 1962.
3 Figgis, B. N. An Introduction to Ligand Fields; Wiley Eastern: New Delhi, 1976.
4 Dendrinou-Samara, C.; Psomas, G.; Raptopoulou, C. P.; Kessissoglou, D. P. J. Inorg. Biochem. 2001, 83, 7.   DOI
5 EL-Shwiniy, W. H.; EL-Attar, M. S.; Sadeek, S. A. J. Korean Chem. Soc. 2013, 57, 52.   DOI
6 Raman, N.; Sakthivel, A.; Rajasekaran, K. Mycobiology 2007, 35(3), 150.
7 Imran, M.; Iqbal, S.; Ijaz, N. Turk. J. Biol. 2007, 31, 67.
8 Regulska, E.; Samsonowicz, M.; Swislocka, R.; Lewandowski, W. J. Phys. Org. Chem. 2007, 20, 93.   DOI   ScienceOn
9 Mehrotra, R. C.; Bohra, R. Metal Carboxylates; Academic Press: London, 1983.
10 Mehrotra, R. C.; Singh, A. Prog. Inorg. Chem. 1997, 46, 239-454.   DOI
11 Bharti, N.; Maurya, R. M.; Bhattacharya, A.; Bhattacharya, S.; Azam, A. Eur. J. Med. Chem. 2000, 35, 481.   DOI
12 STANILA, Andreea; BRAICU, Cornelia; STANILA, Sorin; POP, M. Raluca. Not. Bot. Horti. Agrobo. 2011, 39, 124.
13 Stuhlmeier, K. M.; Li, H.; Kao, J. J. Biochem. Pharmacol. 1999, 57, 313.   DOI
14 Dendrinou-Samara, C.; Tsotsou, G.; Ekateriniadou, L. V.; Kortsaris, A. H.; Raptopoulou, C. P.; Terzis, A.; Kyriakidis, D. A.; Kessissoglou, D. P. J. Inorg. Biochem. 1998, 71, 171.   DOI
15 Nadzhafov, G. N.; Shnulin, A. N.; Mamedov, Kh, S. Zh. Strukt. Khim. 1981, 22, 124.
16 Kristiansson, O. Z. Kristallogr New Cryst. Struct. 2001, 216, 86.
17 Sheldrick, G. M. Acta Crystallogr. Sect. A 2008, 64, 112.   DOI   ScienceOn
18 Dhanya, V. S.; Sudarsanakumar, M. R.; Suma, S.; Prasanna, S.; Rajendra Babu, K.; Sureshkumar, B.; Sunalya, M. Roy J. Cryst. Growth 2011, 319, 96.   DOI
19 Sunalya, M. Roy; Sudarsanakumar, M. R.; Suma, S.; Prathapachandra Kurup, M. R.; Dhanya, V. S. J. Inorg. Organomet. Polym. 2013, 23, 608-615.   DOI
20 Altornare, A.; Cascarano, G.; Giacovazzo, C.; Guagliardi, A. J. Appl. Cryst. 1993, 26, 343.   DOI   ScienceOn
21 Mercury 1.4.1, Copyright Cambridge Crystallographic Data Center, Cambridge (2001/2005).
22 Srinivasan, B. R.; Rane, G. K. J. Chem. Sci. 2009, 121, 145.   DOI
23 Srinivasan, B. R.; Sawant, S. C. Thermochimic. Acta 2003, 402, 45.   DOI
24 Regulska, E.; Samsonowicz, M.; Swislocka, R.; Lewandowski, W. J. Phys. Org. Chem. 2007, 20, 93.   DOI   ScienceOn
25 Srinivasan, B. R.; Shetgaonkar, S. Y.; Nather, C.; Bensch, W. Polyhedron 2009, 28, 534.   DOI
26 Lever, A. B. P. Inorganic electronic spectroscopy, 2nd ed.; Elsevier: Amsterdam, 1984; pp 376.
27 Figgis B. N.; Lewis J. Progr. Inorg. Chem. 1964, 6, 37.   DOI
28 Hassaan, A. M. A. Trans. Met. Chem. 1990, 15, 283.   DOI
29 Dhanya, V. S.; Sudarsanakumar, M. R.; Suma, S.; Prathapachandra Kurup, M. R.; Sithambaresan, M.; Sunalya, M. Roy Specrochim. Acta A 2012, 93, 295.   DOI
30 Srinivasan, B. R.; Sarvesh, C. Sawant Indian J. Chem. 2004, 43A, 1066.
31 Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th ed.; Wiley: New York, 1986.
32 Brandenburg, K. DIAMOND, version 3.1f; Crystal Impact GbR: Bonn, Germany 2008.