Browse > Article
http://dx.doi.org/10.5012/jkcs.2014.58.1.85

Inhibiting Effect of Nicotinic Acid Hydrazide on Corrosion of Aluminum and Mild Steel in Acidic Medium  

Bhat, J. Ishwara (Department of Chemistry, Mangalore University)
Alva, Vijaya D.P. (Department of Chemistry, Shree Devi Institute of Technology)
Publication Information
Journal of the Korean Chemical Society / v.58, no.1, 2014 , pp. 85-91 More about this Journal
Abstract
The corrosion behavior of aluminum and mild steel in hydrochloric acid medium was studied using a nicotinic acid hydrazide as inhibitor by potentiodynamic polarization, electrochemical impedance spectroscopy technique and gravimetric methods. The effects of inhibitor concentration and temperature were investigated. The experimental results suggested, nicotinic acid hydrazide is a good corrosion inhibitor for both aluminum and mild steel in hydrochloric acid medium and the inhibition efficiency increased with increase in the inhibitor concentration. The polarization studies revealed that nicotinic acid hydrazide exhibits mixed type of inhibition. The inhibition was assumed to occur via adsorption of the inhibitor molecules on the aluminum and mild steel surface and inhibits corrosion by blocking the reaction sites on the surface of aluminum.
Keywords
Nicotinic acid hydrazide; Aluminum; Mild steel; Corrosion;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Tamil, S. S.; Raman, V.; Rajendran, N. J. Appl. Electrochem. 2003, 33, 1175.   DOI   ScienceOn
2 Solmaz, R.; Kardas, G.; Culha, M.; Yazici, B.; Erbil, M. Electrochim. Acta 2008, 53, 5941.   DOI   ScienceOn
3 Schmitt, G. Bri. Corros. J. 1984, 19, 165.   DOI   ScienceOn
4 Hasanov, R.; Sadikoglu, M.; Bilgic, M. Appl. Surf. Sci. 2007, 253, 3913.   DOI   ScienceOn
5 Chetouani, A.; Hammouti, B.; Benhadda, T.; Daoudi, M. Appl. Surf. Sci. 2005, 249, 375.   DOI   ScienceOn
6 Yildirim, A.; Cetin, M. Corros. Sci. 2008, 50, 155.   DOI   ScienceOn
7 Obot, I. B.; Obi-Egbedi, N. O. Colloids Surf. A Physiochem. Eng. Ascepts 2008, 330, 207.   DOI   ScienceOn
8 Khaled, K. F.; Al-Qahtani, M. M. Matter. Chem. Phys. 2009, 113, 150.   DOI   ScienceOn
9 Ma, H.; Song, T.; Sun, H.; Li, X. Thin Solid Films 2008, 516, 1020.   DOI   ScienceOn
10 Ju, H.; Kai, Z. P.; Li, Y. Corros. Sci. 2008, 50, 865.   DOI   ScienceOn
11 Ebenso, E. E. Mater. Chem. Phys. 2003, 79, 58.   DOI   ScienceOn
12 Zerga, B.; Attayibat, A.; Sfaira, M.; Taleb, M.; Hammouti, B.; Ebn, T. M.; Radi, S.; Rais, Z. J. Appl. Electrochem. 2010, 40, 1575.   DOI
13 Xiang-Hong, L.; Shu-Dhuan, D.; Hui, F. J. Appl. Electrochem. 2010, 40, 1641.   DOI
14 Sekin, I.; Sabongi, M.; Hagiuda, H.; Oshibe, T.; Yuasa, M.; Imahc, T.; Shibata, Y.; Wake, T. J. Electrochem. Soc. 1992, 139, 3167.   DOI
15 Poornima, T.; Jagannath, N.; Nityananda, S. A., J. Appl. Electrochem. 2010, 41, 223.
16 Aljourani, J.; Raeissi, K.; Golozar, M. A. Corros. Sci. 2009, 51, 1836.   DOI   ScienceOn
17 Khaled, K. F. Electrochim. Acta. 2003, 48, 2493.   DOI   ScienceOn
18 Cruz, J.; Martinez, R.; Genesca, J.; Garcia-Ochoa, E. J. Electroanal. Chem. 2004, 566, 111.   DOI   ScienceOn
19 QiBo, Z.; YiXin, H. Mater. Chem. Phys. 2010, 119, 57   DOI   ScienceOn
20 Khaled K. F. Corros. Sci. 2010, 52, 2905.   DOI   ScienceOn
21 Jones, D. A. Principles and Prevention of Corrosion; Prentice Hall: New York, 1996.
22 Jyotsna, S.; Pitre, K. S. Bull. Electrochem. 2004, 20, 309.
23 Bereket, G.; Ogretir, C.; Yurt, A. J. Mol. Struct. 2001, 571,139.   DOI   ScienceOn
24 Du, T.; Chen, J.; Cao, D. J. Mater. Sci. 2001, 36, 3903.   DOI   ScienceOn
25 Branzoi, V.; Florentian, G.; Florina, B. Mater. Chem. Phys. 2003, 78, 122.   DOI   ScienceOn
26 Obot, I. B.; Obi-Egbedi, N. O.; Umoren, S. A. Corros. Sci. 2009, 51, 1868.   DOI   ScienceOn
27 Zerfaoui, M.; Oudda, H.; Hammouti, B.; Kertit, S. Prog. Org. Coat. 2004, 51, 134.   DOI   ScienceOn
28 Mohamed Awad K., J. Electroanal. Chem. 2004, 567,219.   DOI   ScienceOn
29 Ramesh, S. V.; Vasudeva, A. A. Corros. Sci. 2008, 50, 55.   DOI   ScienceOn
30 Bastidas, J. M.; Polo, J. L.; Cano, E. J. Appl. Electrochem. 2000, 10, 1173.
31 Emrgul, K. C.; Akay, A. A.; Atakol, O. Mater. Chem. Phys. 2005, 93, 325.   DOI   ScienceOn