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http://dx.doi.org/10.5012/jkcs.2013.57.2.252

DABCO-Catalyzed Green Synthesis of 2-Hydroxy-1,4-diones via Direct Aldol Reaction of Arylglyoxals in Water  

Saraei, Mahnaz (Department of Chemistry, Payame Noor University)
Eftekhari-Sis, Bagher (Department of Chemistry, University of Maragheh)
Mozaffarnia, Sakineh (Department of Chemistry, University of Maragheh)
Publication Information
Journal of the Korean Chemical Society / v.57, no.2, 2013 , pp. 252-259 More about this Journal
Abstract
A green and simple method to synthesize of 1,4-diketones via aldol reaction of arylglyoxals and ketones such as 1-(4-methoxyphenyl)-2-propanone, deoxybenzoin and substituted acetophenones in the presence of a catalytic amount of DABCO in water at room temperature has been reported. Corresponding 2-hydroxy-1,4-diones were obtained in moderate to high yields with simple separation of obtained solid from reaction mixture and recrystallization.
Keywords
1,4-Diketones; Aldol reaction; Arylglyoxals; DABCO; Green chemistry;
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