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http://dx.doi.org/10.5012/jkcs.2012.56.6.720

Micellar Catalysis on 1,10-Phenanthroline Promoted Chromic Acid Oxidation of Ethane-1,2-diol in Aqueous Media at Room Temperature  

Ghosh, Sumanta K. (Homogeneous Catalysis Laboratory, Department of Chemistry, The University of Burdwan)
Saha, Rumpa (Homogeneous Catalysis Laboratory, Department of Chemistry, The University of Burdwan)
Ghosh, Aniruddha (Homogeneous Catalysis Laboratory, Department of Chemistry, The University of Burdwan)
Basu, Ankita (Homogeneous Catalysis Laboratory, Department of Chemistry, The University of Burdwan)
Mukherjee, Kakali (Homogeneous Catalysis Laboratory, Department of Chemistry, The University of Burdwan)
Saha, Indrajit (Homogeneous Catalysis Laboratory, Department of Chemistry, The University of Burdwan)
Saha, Bidyut (Homogeneous Catalysis Laboratory, Department of Chemistry, The University of Burdwan)
Publication Information
Journal of the Korean Chemical Society / v.56, no.6, 2012 , pp. 720-724 More about this Journal
Abstract
Under pseudo-first order conditions, the monomeric species of Cr(VI) was found to be kinetically active in the absence of phenanthroline (phen) whereas in the phen-promoted path, the Cr(VI)-phen complex undergoes a nucleophilic attack by etane-1,2-diol to form a ternary complex which subsequently experience a redox decomposition leading to hydroxy ethanal and Cr(III)-phen complex. The effect of the cationic surfactant (CPC), anionic surfactant (SDS) and neutral surfactant (TX-100) on the unpromoted and phen-promoted path have been studied. Micellar effects have been explained by considering the preferential partitioning of reactants between the micellar and aqueous phase. Combination of TX-100 and phenanthroline will be the ideal for chromic acid oxidation of ethane-1,2-diol in aqueous media.
Keywords
1,10-Phenanthroline; Ethane 1,2-diol; SDS; CPC; TX-100;
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1 Dwars, T.; Paetzold, E.; Oehme, G. Angew. Chem. 2005, 117, 7338.   DOI
2 Seo, S. H.; Chang, J. Y.; Tew, G. N. Angew. Chem., Int. Ed. 2006, 45, 7526.   DOI   ScienceOn
3 Minkler, S. R. K.; Lipshutz, B. H.; Kravse, N. Angew. Chem. 2011, 123, 1966.
4 Mandal, J.; Chowdhury, K. M.; Paul, K.; Saha, B.; J. Coord. Chem. 2010, 63, 99.   DOI
5 Chowdhury, K. M.; Mandal, J.; Saha, B. J. Coord. Chem. 2009, 62, 1871.   DOI
6 Islam, M.; Saha, B.; Das, A. K. J. Mol. Catal A: Chem. 2007, 266, 21.   DOI   ScienceOn
7 Islam, M.; Saha B.; Das, A. K.; J. Mol. Catal A: Chem. 2005, 236, 260.   DOI   ScienceOn
8 Sundaram, S.; Raghavan, S. Chromium-VI Reagents: Synthetic Applications; Springer: 2011.
9 Anastas, P. T.; Williamson, T. C. Green Chemistry: An Overview; ACS Symposium Series: 1996; Chapter 1, pp 1-17.
10 Das, A. K.; Roy, A., Saha, B.; Mohanty, R. K.; Das, M.; J. Phys. Org. Chem. 2001, 14, 333.   DOI
11 Vogel, A. I. Elementary Practical Organic Chemistry, Part III, Quantitative Organic Analysis; ELBS and Longman Group Ltd.: London, 1958; p 739.
12 Das, A. K.; Roy, A.; Saha, B. Transition Met. Chem. (Dordrecht, Neth.) 2001, 26, 630.   DOI
13 Ghosh, S. K.; Saha, R.; Mukherjee, K.; Ghosh, A.; Bhattacharyya, S. S.; Saha, B. J. Korean Chem. Soc. 2012, 56, 164.   DOI   ScienceOn
14 Ghosh, A.; Saha, R.; Mukherjee, K.; Ghosh, S. K.; Bhattacharyya, S. S.; Saha, B. J. Chem. Res. 2012, 347.
15 Ghosh, S. K.; Basu, A.; Saha, R.; Ghosh, A.; Mukherjee, K.; Saha, B. J. Coord. Chem. 2012, 65, 1158.   DOI
16 Ghosh, S. K.; Basu, A.; Saha, R.; Nandi. R.; Saha, B. Current Inorg. Chem. 2012, 2, 86.   DOI
17 Saha, R.; Ghosh, A.; Saha, B. J. Coord. Chem. 2011, 64, 3729.   DOI
18 Meenakshisundaram, S. P.; Gopalkrishnan, M.; Nagrajan, S.; Sarathi, N. Catal. Commun. 2007, 8, 713.   DOI
19 Ghosh, A.; Saha, R.; Ghosh, S. K.; Mukherjee, K.; Bhattacharyya, S. S.; Laskar, S.; Saha, B. Int. J. Chem. Kinet., in press. DOI:10.1002/kin.20754.   DOI   ScienceOn
20 Mukherjee, K.; Saha, R.; Ghosh, A.; Ghosh, S. K.; Saha, B. Spectrochim. Acta, Part A, in press.