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http://dx.doi.org/10.5012/jkcs.2012.56.4.484

Preparation, Characterization and Catalytic Activity of Tin Dioxide and Zero-Valent Tin Nanoparticles  

Pouretedal, H.R. (Faculty of Applied Chemistry, Malek-ashtar University of Technology)
Shafeie, A. (Department of Chemistry, Islamic Azad University)
Keshavarz, M.H. (Faculty of Applied Chemistry, Malek-ashtar University of Technology)
Publication Information
Journal of the Korean Chemical Society / v.56, no.4, 2012 , pp. 484-490 More about this Journal
Abstract
The tin (IV) oxide nanoparticles are prepared by controlled precipitation method and calcined at temperatures of $200-600^{\circ}C$. The prepared $SnO_2$ nanoparticles characterized by XRD patterns, TEM image, IR and UV-Vis spectra. The XRD patterns and TEM image show the tetragonal structure and spherical morphology for $SnO_2$ nanoparticles, respectively. The photocatalytic activity of the prepared $SnO_2$ nanoparticles studied in degradation reaction of methylene blue (MB). The results show the size of nanoparticles, band-gap energy and photocatalytic activity of $SnO_2$ depends on the calcinations temperature. The $SnO_2$ nanoparticles calcined at $500^{\circ}C$ indicated the highest photoreactivity. Also, the zero-valent tin (ZVT) nanoparticles with tetragonal structure are prepared by a reducing agent and used as a catalyst in degradation of MB. In basic pH of 11, the degradation >95% of MB at time 150 min obtained at presence of ZVT nanoparticles.
Keywords
$SnO_2$; Sn; Nanoparticles; Methylene blue; Photocatalyst;
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