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http://dx.doi.org/10.5012/jkcs.2012.56.4.468

Microwave-assisted Synthesis of Benzo-[1,4]-oxazinones Using MeO-PEG-OMe as Solvent  

Lim, Jae-Min (Department of Chemistry, College of Natural Science, Changwon National University)
Gam, Gyung-Hee (Department of Chemistry, College of Natural Science, Changwon National University)
Kim, Shin-Hyuong (Department of Chemistry, College of Natural Science, Changwon National University)
Jang, Ki-Wan (Department of Physics, College of Natural Science, Changwon National University)
Shin, Dong-Soo (Department of Chemistry, College of Natural Science, Changwon National University)
Publication Information
Journal of the Korean Chemical Society / v.56, no.4, 2012 , pp. 468-472 More about this Journal
Abstract
Efficient one-pot microwave-assisted synthesis of various benzo-[1,4]-oxazinones via Smiles rearrangement is described. Treatment of 2-chloroacetamide, substituted 2-chlorophenols and cesium carbonate in MeO-PEG-OMe (2,000) as solvent afforded the corresponding benzo-[1,4]-oxazinones and 1H-pyrido[2,3-b][1,4]-oxazin-2-(3H)-one as moderate yield.
Keywords
Benzo-[1,4]-oxazinone; Microwave-assisted; MeO-PEG-OMe; Pyrido-[1,4]-oxazinone; Smiles rearrangement;
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