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http://dx.doi.org/10.5012/jkcs.2012.56.3.316

PEG-Mediated Catalyst-Free Expeditious Synthesis of Functionalized Benzene/Biaryl and Fluoren-9-one Derivatives from Activated Acetylenes and 1,3-Diones  

Piltan, Mohammad (Department of Chemistry, Sanandaj Branch, Islamic Azad University)
Yavari, Issa (Department of Chemistry, Tarbiat Modares University)
Moradi, Loghman (Department of Chemistry, University of Kurdistan)
Zarei, Seyed Amir (Department of Chemistry, Sanandaj Branch, Islamic Azad University)
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Abstract
Poly(ethylene glycol) (PEG) has been used as a sustainable, non-volatile, and environmentally friendly reaction solvent for the synthesis of functionalized benzene/biaryl and fluoren-9-one derivatives from activated acetylenes and 1,3-diones at $100^{\circ}C$. No additional solvent and catalyst are required.
Keywords
Biaryl; PEG; 1,3-Diones; Fluoren-9-one;
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