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http://dx.doi.org/10.5012/jkcs.2011.55.4.666

One-pot Synthesis of Dihydropyrimidinones Using Polyoxometalate Tri-supported Transition Metal Complexes  

Fazaeli, Razieh (Department of Chemistry, Islamic Azad University)
Aliyan, Hamid (Department of Chemistry, Islamic Azad University)
Mohammadifar, Foroogh (Department of Chemistry, Islamic Azad University)
Zamani, Amir Abbas (Department of Chemistry, Islamic Azad University)
Bagi, Mohammad Javad (Department of Chemistry, Islamic Azad University)
Publication Information
Journal of the Korean Chemical Society / v.55, no.4, 2011 , pp. 666-672 More about this Journal
Abstract
The catalytic activity of an inorganic-organic complex with a vanadium-substituted polyoxometalate 1, formulated as [Cu(2,2'-bipy)]$[Cu(2,2 was studied in the Biginelli reactions. The obtained results showed that, in the one-pot synthesis of dihydropyrimidinones, the turnover frequencies (TOF) for the [Cu(2,2'-bipy)]$[Cu(2,2 catalyst were higher than the $H_3PMo_{12}O_{40}$ catalyst.
Keywords
Keggin molybdenum-vanadium heteropolyoxoanions; Dihydropyrimidinones (DHPMs); Polyoxometalates (POMs); inorganic-organic complex;
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