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http://dx.doi.org/10.5012/jkcs.2011.55.4.644

Polyaniline/SiO2 Catalyzed One-pot Mannich Reaction: An Efficient Synthesis of β-amino Carbonyl Compounds  

Yelwande, Ajeet A. (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University)
Arbad, Balasaheb R. (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University)
Lande, Machhindra K. (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University)
Publication Information
Journal of the Korean Chemical Society / v.55, no.4, 2011 , pp. 644-649 More about this Journal
Abstract
Polyaniline/$SiO_2$ catalyzed one-pot mannich reaction of acetophenone, aromatic aldehydes and aromatic amines are carried out in ethanol to afford various ${\beta}$-amino ketones. The various wt% of polyaniline were supported on pure silica synthesized by using chemical oxidative method. The catalyst prepared has been characterized by means of thermal analysis (TG-DTA), X-ray diffraction (XRD), scanning electron microscopy (SEM) energy dispersive spectroscopy (EDS), and Fourier transform infrared spectroscopy (FT-IR). Solvent stability of catalyst was tested using UV-Visible spectroscopy. This protocol has several advantages such as high yield, simple work up procedure, non-toxic, clean, easy recovery and reusability of the catalyst.
Keywords
Chemical oxidative method; Polyaniline/$SiO_2$; Mannich reaction; ${\beta}$-amino carbonyl compounds;
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