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http://dx.doi.org/10.5012/jkcs.2011.55.4.590

Synthesis and Characterization of a Novel Organotin Complex: Di(n-butyl) chloro[5-(p-dimethylaminobenzylidene)rhodanine]tin(IV) Based on a Competing N, O, and S Donor Ligand  

Tarassoli, Abbas (Department of Chemistry, College of Sciences, Shahid Chamran University)
Sedaghat, Tahereh (Department of Chemistry, College of Sciences, Shahid Chamran University)
Mousavi, Fatemeh (Department of Chemistry, College of Sciences, Shahid Chamran University)
Publication Information
Journal of the Korean Chemical Society / v.55, no.4, 2011 , pp. 590-593 More about this Journal
Abstract
A novel organotin(IV) complex has been prepared from $Bu_2SnCl_2$ and the N, O and S donor ligand, 5-(p-dimethylaminobenzylidene) rodanine (HL). The ligand is deprotonated in the presence of a base and the complex with the general formula $SnBuCl_2L$ is formed. This complex was fully characterized by IR, $^1H$ NMR and $^{119}Sn$ NMR and elemental analysis. Spectroscopic data indicate the ligand is coordinated through the oxygen atom to the tin and the coordination number of four is supported by $^{119}Sn$ NMR data in solution.
Keywords
Rhodanine derivatives; Organotin complexes; $^{119}Sn$ NMR; Donor ligand;
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