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http://dx.doi.org/10.5012/jkcs.2011.55.3.412

Synthesis and Characterization of Homobinuclear Complexes of UO2(VI), ZrO(IV) and Th(IV) ions with 3-Benzylidine/Furfurylidine/(Pyridyl/Thienyl-2'-methylene) imino-5-p-sulphonamido phenyl azo-2-thiohydantoins  

Dash, D.C. (School of Chemistry, Sambalpur University)
Mahapatra, A. (School of Chemistry, Sambalpur University)
Naik, P. (School of Chemistry, Sambalpur University)
Mohapatra, R.K. (School of Chemistry, Sambalpur University)
Naik, S.K. (School of Chemistry, Sambalpur University)
Publication Information
Journal of the Korean Chemical Society / v.55, no.3, 2011 , pp. 412-417 More about this Journal
Abstract
A series of homobinuclear complexes of the type [$M_2L(NO_3)_n(H_2O)_m$] where M=$UO_2$(VI), ZrO(IV), Th(IV); L=3-benzylidine-imino-5-p-sulphonamido phenyl azo-2-thiohyatoin(bispt), 3-furfurylidine-imino-5-p-sulphonamido phenyl azo-2-thiohydantoin(fispt),3-pyridyl-2'-methylene-imino-5-p-sulphonamido phenyl azo-2-thiohydantoin(pmispt) and 3-thienyl-2'-methylene-imino-5-p-sulphoanamido phenyl azo-2-thiohydantoin(tmispt); n=8 for Th(IV) and 4 for others, m=4 for bispt and 3 for others have been synthesized and characterized on the basis of elemental analysis, thermal analysis, molar conductance, magnetic moment and spectroscopic data (IR, electronic and $^1H$-NMR). In the light of this information, the ligands can be visualized as tetradentate co-ordinating through azomethine nitrogen, carbonyl oxygen to one metal centre where as azo nitrogen and thioimido nitrogen to the other metal centre yielding homo binuclear complexes of the above composition. The fungi toxicity of the ligands & their zirconyl complexes against some fungal pathogen has been studied.
Keywords
3-substituted thiohydantoin; Structure and Thermal Properties; IR and $^1H$ NMR spectra;
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