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http://dx.doi.org/10.5012/jkcs.2010.54.4.402

Synthesis and Characterization of New Transition Metal Complexes of Schiff-base Derived from 2-Aminopyrimidine and 2,4-Dihydroxybenzaldehyde and Its Applications in Corrosion Inhibition  

Ouf, Abd El-Fatah M. (Chemistry Department, Faculty of Science, Mansoura University)
Ali, Mayada S. (Chemistry Department, Faculty of Science, Mansoura University)
Soliman, Mamdouh S. (Chemistry Department, Faculty of Science, Mansoura University)
El-Defrawy, Ahmed M. (Chemistry Department, Faculty of Science, Mansoura University)
Mostafa, Sahar I. (Chemistry Department, Faculty of Science, Mansoura University)
Publication Information
Journal of the Korean Chemical Society / v.54, no.4, 2010 , pp. 402-410 More about this Journal
Abstract
New complexes cis-[$Mo_2O_5(Hapdhba)_2$], trans-[$UO_2(Hapdhba)_2$], [Pd(Hapdhba)Cl($H_2O$)], [Pd(bpy)(Hapdhba)]Cl, [Ag(bpy)(Hapdhba)], [$Ru(Hapdhba)_2(H_2O)_2$], [$Rh(Hapdhba)_2Cl(H_2O)$] and [Au(Hapdhba)$Cl_2$] are reported, where $H_2$apdhba is the Schiff-base derived from 2-aminopyrimidine and 2,4-dihydroxy benzaldehyde. The complexes were characterized by IR, electronic, $^1H$ NMR and mass spectra, conductivity, magnetic and thermal measurements. The inhibitive effect of $H_2$apdhba for the corrosion of copper in 0.5 M HCl was also determined by potentiodynamic polarization measurements.
Keywords
Schiff-base; $H_2$apdhba; Azomethine; Spectra; Polarization;
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Times Cited By KSCI : 3  (Citation Analysis)
Times Cited By SCOPUS : 1
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