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http://dx.doi.org/10.5012/jkcs.2010.54.02.234

Synthesis of Carbonate Derivatives and Derived Cetane Number for the Use of Diesel Additives  

Cho, Chang-Yong (Department of Chemistry, Chungnam National University)
Chung, Keun-Woo (Research Center for Green Chemistry Catalyst, Korea Research Institute of Chemical Technology)
Kim, Young-Wun (Research Center for Green Chemistry Catalyst, Korea Research Institute of Chemical Technology)
Kim, Yeong-Joon (Department of Chemistry, Chungnam National University)
Publication Information
Journal of the Korean Chemical Society / v.54, no.2, 2010 , pp. 234-239 More about this Journal
Abstract
Carbonate derivatives were synthesized for the use of diesel additives and the derived cetane numbers of the derivatives were measured. Some carbonate ester derivatives were synthesized from 1,2-glycerol carbonate and long alkyl chain fatty acids. To improve the solubility, we introduced unsaturated groups into aliphatic carbons and alkyl group into ${\alpha}$-carbon to the carbonyl group. The derived cetane numbers obtained from ASTM method were increased up to 1.0, which means some carbonate derivatives could be potential diesel additives.
Keywords
Cetane number; Carbonate derivatives; Diesel additives;
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