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http://dx.doi.org/10.5012/jkcs.2010.54.01.055

Selective Reduction of Nitro Compounds Using CeY Zeolite Under Microwaves  

Arya, Kapil (Department of Applied science, D. C. R. University)
Dandia, Anshu (Department of Chemistry, University of Rajasthan)
Publication Information
Journal of the Korean Chemical Society / v.54, no.1, 2010 , pp. 55-58 More about this Journal
Abstract
Aliphatic and aromatic nitro compounds were selectively reduced to their corresponding amino derivatives in good yields using formic acid and CeY zeolite under monomode reactor. This system is found to be compatible with several sensitive functionalities. Beside the recycling result showed it had a long catalyst lifetime and could maintain activity even after being used for 20 cycles.
Keywords
CeY zeolite; Monomode reactor; Microwaves; Reduction; Nitro compounds;
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1 Dyer, A. An Introduction to Zeolite Molecular Sieves, Wiley, Chichester, 1988.
2 Holderich, W.; Hesse, M.; Näumann, F. Angew. Chem. Int. Ed. Engl. 1988, 27, 226.   DOI
3 Smith, K. Stud. Surf. Sci. Catal. 1991, 59, 55.   DOI
4 Ehernkaufer, R.; Ram, S. Tetrahedron Lett. 1984, 25, 3415.   DOI
5 Walls, F.; Saldana, M.; Yuste, F. Tetrahedron Lett. 1982, 23, 147.   DOI
6 Lyle, R. E.; Lamittina, J. L. Synthesis 1974, 726.
7 Ho, T. L.; Wang, C. M. Synthesis 1977, 756.
8 Onochenko, A.; Sabourin, E. T.; Selwitz, C. M. J. Org. Chem. 1979, 44, 3671.   DOI
9 Larock, R. C. Comprehensive organic Transformations - A Guide to Functional Groups preparations; VCH publishers. Inc., New York, 1989, p 412.
10 Prajapati, D.; Borah, H. N.; Sandhu, J. S.; Ghosh, A. C. Synth. Commun. 1995, 25, 4025.   DOI
11 Akita, Y.; lnaba, M.; Uchida, H.; Ohta, A. Synthesis 1977, 792.
12 Osuka, A.; Shimizu, H.; Suzuki, H. Chem. Lett. 1993, 1373.
13 George, J.; Chandrashekaran, S. Synth. Commun. 1983, 495.
14 Finbeiner, H. L.; Stiles, M. J. Am. Chem. Soc. 1963, 85, 616.   DOI
15 Siegrist, U.; Baumeister, P.; Blaser, H. U.; Studer, M. Chem. Ind. 1998, 75, 207.
16 Nishmura, S. Bull. Chem. Soc. Jpn. 1961, 34, 32.   DOI
17 Adkins, H.; Pavlic, A. A. J. Am. Chem. Soc. 1930, 52, 4349.   DOI
18 Adkins, H.; Connor, R. J. Am. Chem. Soc. 1931, 53, 1091.   DOI
19 Broadbent, H. S.; Slaugh, L. H.; Jarvis, N. L. J. Am. Chem. Soc. 1954, 76, 1519.   DOI
20 Cho, Y. S.; Jun, B. K.; Kim, S.; Cha, J. H.; Pae, A. N.; Koh, H. Y.; Chang, M. H.; Han, S.-Y. Bull. Korean Chem. Soc. 2003, 24, 653.   DOI   ScienceOn
21 Sonavane, S. U.; Jayaram, R. V. Synth. Commun. 2003, 33, 843.   DOI
22 Sartori, G.; Maggi, R. Chem. Rev. 2006, 106, 1077.   DOI
23 Corma, A.; García, H. Chem. Rev. 2003, 103, 4307.   DOI
24 Rashid, B.; Laleh, T. Journal of Inclusion Phenomena and Macrocyclic Chemistry 2003, 45, 41.   DOI
25 Bezouhanova, C. P.; Applied Catalysis A: General 2002, 229, 127.   DOI
26 Stephanie, E. S.; Sarah, M. S.; Katherine, A. S. Tetrahedron 1999, 55, 2657.
27 Finiels, A.; Geneste, P.; Marichez, F.; Moreau, P. Catalysis Letters 1989, 2, 181.   DOI
28 Berlan, J.; Giboreau, P.; Lefeuvre, S.; Marchand, C. Tetrahedron Lett. 1991, 32, 2363.   DOI
29 Lewis, D. A.; Summers, J. D.; Ward, T. C.; McGrath, J. E. J. Polym. Science (A) 1992, 30, 647.
30 Loupy, A. Microwaves in Organic synthesis; Wiley-VCH, Weinheim, 2006.
31 Jeselnik, M.; Varma, R. S.; Polanc, S.; Kocevar, M. Green Chemistry 2002, 4, 35.   DOI
32 Balalaie, S.; Arabanian, A. Green Chemistry 2000, 2, 274.   DOI   ScienceOn
33 Hoelderich, W. F. Appl. Catal. A-Gen. 2000, 194, 487.   DOI
34 Sreekumar, R.; Padmakumar, R.; Rugmini, P. Tetrahedron Lett. 1998, 39, 2695.   DOI
35 Zhang, H.; Li, H.; Lin, G.; Liu, Y.; Tsai, K. R. Stud. Surf. Sci. Catal. 1996, 101, 369.   DOI
36 Dandia, A.; Singh, R.; Arya, K. Letters in Organic chemistry 2009, 6, 100.   DOI
37 Arya, K.; Dandia, A. Bioorg. Med. Chem. Lett. 2008, 18, 114.   DOI
38 Arya, K.; Dandia, A. J. Fluorine Chem. 2007, 128, 224.   DOI
39 Dandia, A.; Arya, K.; Sati, M.; Gautum, S. Tetrahedron 2004, 60, 5253.   DOI
40 Dandia, A.; Sati, M.; Arya, K.; Loupy, A. Heterocycles 2003, 60, 563.   DOI
41 Beaumont, R.; Ha, B. H.; Barthomeuf, D. J. Catal. 1975, 40, 160.   DOI
42 Kappe, C. O.; Stadler, A. Microwaves in Organic and Medicinal Chemistry; Wiley-VCH, Weinheim, 2005.
43 De La, Hoz A; Diaz-Ortiz, A.; Moreno, A. Chem. Soc. Rev. 2005, 34, 164.   DOI
44 Dictionary of organic compounds, CAS # 108-80-5, 2004.
45 Mosby, W. L. J. Org. Chem. 1959, 24, 421.   DOI
46 Breck, D. W. Zeolite Molecular Sieves; Wiley, New York, 1974.
47 Balk, W.; Han, J. L.; Lee, K. C.; Holee, N.; Hyokim, B.; Hahn, J. T. Tetrahedron Lett. 1994, 35, 395.
48 Clark, J. H. Green Chemistry 1999, 1, 1.   DOI
49 Anastas, P. T.; Warner, J. C. Green Chemistry, Theory and Practice, Oxford University Press, 1998.