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http://dx.doi.org/10.5012/jkcs.2010.54.01.027

Platinum/Nickel Catalyzed Selective Hydrosilylation of Alkynes and Alkenes with 1,1'-Bis(dimethylhydrosilyl) Ferrocene  

Kim, Jin-Sik (Department of Chemistry, Kyonggi University)
Kong, Young-Kun (Department of Chemistry, Kyonggi University)
Publication Information
Journal of the Korean Chemical Society / v.54, no.1, 2010 , pp. 27-37 More about this Journal
Abstract
The reaction of 1,1'-bis(dimethylhydrosilyl)ferrocene with alkynes in the presence of a catalytic amount of ($C_2H_4$)Pt$(PPh_3)_2$ leads to the acyclic mixture of monohydrosilylated and/or dihydrosilylated compounds. But the analogous reactions in the presence of Ni$(PEt_3)_4$ catalyst yield monohydrosilylated compounds or dihydrosilylated products. The monohydrosilylated products were generated from the reactions of alkenes with the silylated ferrocene using nickel catalyst.
Keywords
1,1'-Bis(dimethylhydrosilyl)ferrocene; Hydrosilylation; Dihydrosilylation; Alkynes; Alkenes;
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