Browse > Article
http://dx.doi.org/10.5012/jkcs.2009.53.5.553

Microwave-Syntheses of Zeolitic Imidazolate Framework Material, ZIF-8  

Park, Jung-Hwa (Department of Chemistry, Kyungpook National University)
Park, Seon-Hye (Department of Chemistry, Kyungpook National University)
Jhung, Sung-Hwa (Department of Chemistry, Kyungpook National University)
Publication Information
Journal of the Korean Chemical Society / v.53, no.5, 2009 , pp. 553-559 More about this Journal
Abstract
One of zeolitic imidazolate framework materials (ZIF), ZIF-8, has been synthesized with microwave irradiation and conventional electric heating at $140{\sim}180^{\circ}C}$. ZIFs are porous crystalline materials and are similar to metal organic framework (MOF) materials because both ZIFs and MOFs are composed of both organic and metallic components. ZIFs are very stable and similar to zeolites because ZIFs have tetrahedral networks. ZIF-8, with a decreased crystal size, can be synthesized rapidly with microwave irradiation. The microwave synthesis of ZIF-8 is completed in 4 h at $140{^{\circ}C}$ and the reaction time is decreased by about 5 times compared with the conventional electric heating. The ZIF-8 obtained by microwave heating has larger surface area and micropore volume compared with the ZIF-8 synthesized with conventional electric heating. It can be confirmed that ZIF-8s show type-I adsorption isotherms, explaining the microporosity of the ZIF-8s. Based on FTIR and TGA results, it can be understood that the ZIF-8s have similar bonding and thermal characteristics irrespective of heating methods such as microwave and conventional heating.
Keywords
ZIF-8; microwaves; synthesis; ZIF; MOF;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
Times Cited By SCOPUS : 3
연도 인용수 순위
1 Jhung, S. H.; Jin, T.; Hwang, Y. K.; Chang, J. S. Chem. Eur. J. 2007, 13, 4410   DOI   ScienceOn
2 Jhung, S. H.; Chang, J.-S., et al. unpublished result
3 Kaye, S. S.; Dailly, A.; Yaghi, O. M.; Long, J. R. J. Am. Chem. Soc. 2007, 129, 14176   DOI   ScienceOn
4 Losilla, J. A.; Balkus, K. Abstracts of Papers, 235th ACS National Meeting, New Orleans, LA, United States, April 6-10, 2008, INOR-968
5 Xu, X.; Yang, W.; Liu, J.; Lin, L. Adv. Mater. 2000, 12, 195   DOI   ScienceOn
6 Jhung, S. H.; Chang, J.-S.; Hwang, Y. K.; Grenéche, J.-M.; Férey, G.; Cheetham, A. K. J. Phys. Chem. B. 2005, 109, 845   DOI   ScienceOn
7 Park, S.-E.; Chang, J.-S.; Hwang, Y. K.; Kim, D. S.;Jhung, S. H.; Hwang, J.-S. Catal. Survey Asia 2004, 8, 91   DOI   ScienceOn
8 Tompsett, G. A.; Conner, W. C. ; Yngvesson, K. S. Chem. Phys. Chem. 2006, 7, 296   DOI   ScienceOn
9 Hwang, Y. K.; Chang, J.-S.; Park, S.-E.; Kim, D.S.; Kwon, U. K.; Jhung, S. H.; Hwang, J.-S.; Park, M.S. Angew. Chem. Int. Ed. 2005, 45, 556
10 Jhung, S.H.; Chang, J.-S.; Hwang, Y. K.; Park, S.-E. J. Mater.Chem. 2004, 14, 280   DOI   ScienceOn
11 Son, W.-J.;Kim, J.; Kim, J.; Ahn, W.-S. Ahn, Chem. Commun.2008, 6336
12 Losilla, J. A.; Balkus, K. Abstracts of Papers, 233rd ACS National Meeting, Chicago, IL, United States, March 25-29, 2007, INOR-1243
13 Jhung, S. H.; Lee, J. H.;Chang, J.-S. Micropor. Mesopor. Mater. 2008, 112,178   DOI   ScienceOn
14 Jhung, S. H.; Chang, J.-S.; Hwang, J. S.; Park, S.-E. Micropor. Mesopor. Mater. 2003, 64, 33   DOI   ScienceOn
15 Jhung, S. H.; Lee, J.-H.; Yoon, J. W.; Hwang, Y.K.; Hwang, J.-S.; Park, S.-E.; Chang, J.-S. Mater.Lett. 2004, 58, 3161   DOI   ScienceOn
16 Jhung, S. H.; Chang, J.-S.;Yoon, J. W.; Grenéche, J.-M.; Férey, G.; Cheetham, A. K. Chem. Mater. 2004, 16, 5552   DOI   ScienceOn
17 Jhung, S. H.; Yoon, J. W.; Hwang, J.-S.; Cheetham, A. K.; Chang, J.-S. G.; Chem. Mater. 2005, 17, 4455   DOI   ScienceOn
18 Ferey, G. Chem. Soc. Rev. 2008, 37, 191   DOI   ScienceOn
19 Hayashi, H.; Côté, A. P.; Furukawa, H.; O'Keeffe, M.; Yaghi, O. M. Nat. Mater. 2007, 6, 501   DOI   ScienceOn
20 Park, K. S.; Ni, Z.; Côté, A. P.; Choi, J. Y.; Huang, R.;Uribe-Romo, F. J.; Chae, H. K.; O'Keeffe, M.; Yaghi, O. M. Proc. Natl. Acad.Sci., U.S.A. 2006, 103, 10186   DOI   ScienceOn
21 Banerjee, R.; Phan, A.; Wang, B.; Knobler, C.; Furukawa, H.; O'Keeffe, M.; Yaghi, O. M. Science 2008, 319, 939   DOI   ScienceOn
22 Wang, B.; Côté, A. P.; Furukawa, H.;O'Keeffe, M.; Yaghi, O. M. Nature 2008, 453, 207   DOI   ScienceOn
23 Wu, H.; Zhou W.; Yildirim T. J. Phys. Chem. C 2009, 113, 3029   DOI   ScienceOn
24 Wu, H.; Zhou, W.; Yildirim, T. J. Am. Chem. Soc. 2007, 129, 5314   DOI   ScienceOn
25 Cravillon, J.; Munzer, S.; Lohmeier, S.-J.; Feldhoff, A.; Huber, K.; Wiebcke, M. Chem. Mater. 2009, 21, 1410   DOI
26 Yoon, J. W.; Jhung, S. H.; Kim, Y. H.; Park, S.-E.;Chang, J.-S. Bull. Kor. Chem. Soc. 2005, 26, 558;   DOI   ScienceOn
27 Jhung, S. H.; Lee, J.-H.; Yoon, J. W.; Serre, C.;Férey, G.; Chang, J. S. Adv.Mater. 2007, 19, 121   DOI   ScienceOn
28 Jhung, S. H.; Lee, J.-H.; Forster, P. M.; Férey, G.;Cheetham, A. K.; Chang, J. S. Chem. Eur. J. 2006,12, 7899   DOI   ScienceOn
29 Choi, J. Y.; Kim, J.; Jhung, S. H.; Kim, H.-K.; Chang, J.-S.; Chae, H. K. Bull. Kor. Chem. Soc. 2006, 27, 1523   DOI   ScienceOn
30 Ni, Z.; Masel, R. I. J. Am. Chem. Soc. 2006, 128, 12394   DOI   ScienceOn
31 Seo, Y. K.; Hundal, G.; Jang, I. T.; Hwang, Y. K.; Jun, C.-H.; Chang, J.-S. Micropor. Mesopor. Mater. 2009, 119, 331   DOI   ScienceOn
32 Yaghi, O. M.; O'Keeffe, M.; Ockwig, N. W.; Chae, H. K.; Eddaoudi, M.; Kim, J. Nature 2003, 423, 705   DOI   ScienceOn
33 Qiu, L.-G.; Li, Z.-Q.; Wu, Y.; Wang, W.; Xu, T.;Jiang, X. Chem.Commun. 2008, 3642
34 Li, H.; Eddaoudi, M.; O'Keeffe, M.; Yaghi, O. M. Nature 1999, 402, 276   DOI