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http://dx.doi.org/10.5012/jkcs.2008.52.1.023

Simple Heteropoly Acids as Water-Tolerant Catalysts in the Oxidation of Alcohols with 34% Hydrogen Peroxide, A Mechanistic Approach  

Tayebee, Reza (Department of Chemistry, Sabzevar University)
Publication Information
Journal of the Korean Chemical Society / v.52, no.1, 2008 , pp. 23-29 More about this Journal
Abstract
Simple Keggin type tungsten and molybdenum heteropoly acids, H3PW12O40 and H3PMo12O40, were usedas water-tolerant catalysts for the oxidation of alcohols with 34% hydrogen peroxide in normal drinking water. Accordingto our findings, H3PW12O40 may be used as a simple, effective, and cheap catalyst for this type of transformation in nor-mal drinking water with excelent yields. Efects of diferent solvents at 25-80oC and changing concentration of catalystand substrate on the reaction progress were also studied.
Keywords
Oxidation; Heteropoly acid; Catalysis; Hydrogen Peroxide
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