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http://dx.doi.org/10.5012/jkcs.2007.51.2.115

Synthesis, Characterization and Correlation Analysis in Styryl 6-Methoxy-2-Naphthyl Ketones  

Thirunarayanan, G. (Department of Chemistry, Annamalai University)
Publication Information
Journal of the Korean Chemical Society / v.51, no.2, 2007 , pp. 115-124 More about this Journal
Abstract
A series of α, β-unsaturated ketones are synthesized by Crossed - Aldol condensation reaction, from ecofriendly 6-methoxy-2-naphthyl ketones and substituted benzaldehydes under solvent free conditions using silica-sulfuric acid as a catalytic reagent. The yields of ketones are more than 90% and the catalyst was reusable for further run. There is no appreciable decrease in the yield of product and the activity of catalyst. These chalcones were characterized by their physical constants and spectral data (IR, 1H-, 13C-NMR and Mass). These spectral data are subjected to correlate various Hammett substituent constants with single and multiparameter correlation equations. From the results of statistical analysis the influence of electronic effects of substituents on the spectral data of the ketones were explained.
Keywords
Solvent Free Synthesis; Crossed-Aldol Condensation; Environmentally Eco-friendly Benign Reaction; 6-Methoxy-2-naphthyl Chalcones; IR; NMR and Mass Spectra; Correlation Analysis; Electronic;
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Times Cited By KSCI : 2  (Citation Analysis)
Times Cited By SCOPUS : 4
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