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http://dx.doi.org/10.5012/jkcs.2004.48.1.017

Simultaneous Determination of Phthalates(DMP, DEP, DBP, BBP, DEHP, DnOP) by Solid Phase Microextraction-GC/MS  

Lee, Jae-Hee (Korea Water Resources Corporation)
Bae, Jun-Hyun (Department of Environmental Engineering, Anyang University)
Kang, Jun-Gill (Department of Chemistry, Chungnam National University)
Kim, Youn-Doo (Department of Chemistry, Chungnam National University)
Publication Information
Journal of the Korean Chemical Society / v.48, no.1, 2004 , pp. 17-27 More about this Journal
Abstract
A procedure based on solid phase microextraction extraction(SPME)-GC/MS has been developed for the simultaneous analysis of plasticizers. The plasticizers investigated in this study are dimethyl phthalate(DMP), diethyl phthalate(DEP), dibutyl phthalate(DBP), benzylbutyl phthalate(BBP), diethylhexyl phthalate (DEHP), di-n-octyl phthalate(DnOP). The limit of detection(LOD) was 0.163~0.299 with relative standard deciation(RSD) of 5.85~15.80% for these compounds. At water reserviors of Han, Geum, Nakdong and Sumjin rivers, only DBPand DEHP were detected at trace level, 0.192~1.270 ng/ml for DBP and 0.077~1.102 ng/ml for DEHP depending on the river.
Keywords
Solid Phase Microextraction-GC/MS; Plasticizer; Simultaneous Analysis;
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