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http://dx.doi.org/10.5012/jkcs.2003.47.2.104

Self-Assembly of Three-Dimensional Copper(II) Macrocyclic Complex with 2,5-Pyridinedicarboxylate Linked by Hydrogen Bond  

Ki-Young Choi (Department of Chemistry Education, Kongju National University)
Haiil Ryu (Department of Chemistry Education, Kongju National University)
Yong-Son Kim (Department of Chemistry Education, Kongju National University)
Publication Information
Journal of the Korean Chemical Society / v.47, no.2, 2003 , pp. 104-108 More about this Journal
Abstract
The reaction of $[Cu(L)]Cl_2{\cdot}H_2O(L=3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,0^{1.18},0^{7.12}]docosane)$ with 2,5-pyridinedicarboxylate(pdc) led to the formation of $[Cu(L)(H_2O)](pdc){\cdot}6H_2O(1)$. The structure was characterized by X-ray crystallography and spectroscopic method. The coordination geometry around the copper atom is a distorted square-pyramid with four secondary amines of the macrocycle occupying the basal sites and a water molecule at the axial position. Intermolecular hydrogen bonds in 1 form a three-dimensional molecular network.
Keywords
Crystal Structure; Copper(II) Complex; 2,5-Pyridinedicarboxylate; Three-Dimensional Chain;
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