[KSCI] Korea Science Citation Index Service

http://dx.doi.org/10.5012/jkcs.2003.47.1.026

Dimeric Silver(I) Complex: Bis(dipropyldithiophosphato) bis(1,10-phenanthroline) Disilver(I); Dimeric Silver(I) Complex: Bis(dipropyldithiophosphato) bis(1,10-phenanthroline) Disilver(I);Ag₂[Phen]₂[S₂P(OPr)₂]₂

Fang Fang Jian (New Materials & Function Coordination Chemistry Laboratiry, Qingdao University of Science and Technology)
Hai Lian Xiao (New Materials & Function Coordination Chemistry Laboratiry, Qingdao University of Science and Technology)
Huan Xiang Wang (New Materials & Function Coordination Chemistry Laboratiry, Qingdao University of Science and Technology)
Kui Jiao (New Materials & Function Coordination Chemistry Laboratiry, Qingdao University of Science and Technology)

Publication Information

Journal of the Korean Chemical Society / v.47, no.1, 2003 , pp. 26-30 More about this Journal

Abstract

The dinuclear $Ag_2[Phen]_2[S_2P(OPr)_2]_2$ (phen=1,10-phenanthroline; Pr=propyl), was prepared by the reaction of bis(dipropyldithiophosphato) silver(I) complex with 1,10-phenanthroline ligand, and its structure was determined by X-ray crystallography. The two dipropyldithiophosphato ligands each bridge two silver atoms to form an eight-membered $Ag_2S_4P_2$ ring, while the 1,10-phenanthroline molecule coordinates to a silver atom to complete the local tetrahedral geometry for the metal ion. The Ag-S bond distances are 2.559(1) and 2.567(1) ${\AA}$ , and the Ag-N bond distances are 2.366(3) and 2.471(3) ${\AA}$ .

Keywords

Phen Ligand; Crystal Structure; Dimeric Silver(I); Dithiophosphate;

Citations & Related Records

Reference

1	/ [ Sheldrick, G. M. ] / Actc Cryst., Sect. A
2	/ [ Sheldrick, G. M. SHELXTL93 ] / Program for Crystal Structure refinement
3	/ [ Ye,B.H.;Zeng,T.X.;Han,P.;Ji,L.N. ] / Trans. Met. Chem. DOI
4	/ [ Zimina, K.I.;Kotova, G. G.;Sanin, P. I.;Sher, V. V.;Kuzmina, G. N. ] / Neftekhimiya
5	/ [ Fu, Y.J.;Yang, H.;Wang,D.F.;Tang,W.X.;Wu B.M.;Mak, T. C. W. ] / Polyhedran
6	/ [ Fortin, D.;Drouin, M.;Harvey, P. D.;Herring, F. G.;Summers,D.A.;Thompson,R.C. ] / Inorg. Chem. DOI ScienceOn
7	/ [ Nilsson, K.;Oskarsson, A. ] / Acta Chem. Scand.
8	/ [ Perez-Lourido, P. A.;Carcia-Vazquez, J. A.;Romero, J.;Louro,M.S.;Sousa, A.;Chang Q.Y.;Zubieta, J. ] / J. Chem. Soc., Dalton Trans.
9	/ [ Green, D. W;Willhite, G. P. ] / Enhanced Dil REcovery, Textbooks Series
10	/ [ Schramm, L. L. ] / Surfactants Fundamentals and Applications in the petroleum Industry
11	/ [ Austad, T.;Fjelde, I. ] / Anal. Lett. DOI
12	Fjelde, I.;Austad, T. / [] / Colloids Surf. a: Physicochem. Eng.Aspects. DOI ScienceOn
13	/ [ Miles, C. J.;Doerge, D. R.;Bajic, S. ] / Arch. Environ. Contam. Toxicol. DOI
14	/ [ Clark, L. B.;Rosen, R. T.;Hartmann, T. G.;Alaimo, L. H.;Louis, J. B. Hertz, C.;Ho, C. T.;Rosen, J. D. ] / Res.J. Water Pollut. Control. Fed.
15	/ [ Kim, I. A.;Sasinos, F. I.;Rishi, D. K.;Stephens, R. D.;Brown, M. A. J. ] / Chromatogr DOI ScienceOn
16	/ [ Lakshmy, M. N.;Raaidah S. N. ] / J. Chromatogr. A DOI ScienceOn
17	/ [ Benomar, S. H.;Clench, M. R;Allen, D. W. ] / Anal. Chim. Acta DOI ScienceOn
18	Fu, Y. J.; Yang, H. ; Wang, D. F. ; Tang, W. X.; Wu B. M.; Mak, T. C. W. Polyhedran, 1997, 1505.
19	/ [ Harrison, P. G.;Begley,M. J.;Kikabhai, T.;Killer,F. ] / J. Chem. Soc. Dalton Trans.
20	Zimina, K. I.; Kotova, G. G.; Sanin, P. I.; Sher, V. V.; Kuzmina, G. N. Neftekhimiya 1965, 5(4), 629.
21	Fortin, D.; Drouin, M.; Harvey, P. D.; Herring, F. G.; Summers, D. A.; Thompson, R. C. Inorg. Chem., 1999, 38, 1253. DOI ScienceOn
22	Harrison, P. G.; Begley, M. J.; Kikabhai, T.; Killer, F. J. Chem. Soc. Dalton Trans., 1986, 929.
23	Mikhailov, V. V.; Kokhanov, Yu V.; Kazaryan, K.; Matreeva, E. N.; Kozodoi, A. Plast. Massy, 1970, 9, 23.
24	Sheldrick, G. M. Actc Cryst., Sect. A 1969, 46, 467.
25	So, H.; Lin, Y. C.; Huang, G. S.; Chang, S. T. Wear, 1993, 166, 17. DOI ScienceOn
26	Shiomi, M.; Tokashiki, M.; Tomizaawa, H.; Kuribayashi, T. Lubr. Sci., 1989, 1, 134.
27	Castro, J. A.; Romero, J.; Garcia-Vazquez, J. A.; CastiOeiras, A.; Sousa A.; Zubieta, J.; Polyhedron, 1995, 14, 2841. DOI ScienceOn
28	Ye, B. H.; Zeng, T. X.; Han, P.; Ji, L. N. Trans. Met. Chem., 1993, 18, 515. DOI
29	Nilsson, K.; Oskarsson, A. Acta Chem. Scand., 1983, A37, 891.
30	Jian, F. F.; Hao, Q. L.; Yang, X. J.; Lu L. D.; Wang,X.; J. Chem. Crystallogr., 2000, 30(7), 469. DOI ScienceOn
31	Perez-Lourido, P. A.; Garcia-Vazquez, J. A.; Romero, J.; Louro, M. S.; Sousa, A.; Chang Q. Y.; Zubieta, J. J. Chem. Soc., Dalton Trans., 1996, 2047.
32	Perez-Lourido, P.; Garcia-Vazquez, J. A.; Romero, J.; Sousa,A.; Block,E.; Maresca K. P. ; Zubieta, J. Inorg. Chem., 1999, 38, 538. DOI ScienceOn
33	Sheldrick, G. M. SHELXTL93, Program for Crystal Structure refinement, University of Gottingen, Germany, 1993.