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http://dx.doi.org/10.5012/jkcs.2002.46.5.427

Fe-H…H-C Dihydrogen Bondings: Synthesis and Structure of trans-[FeH(NCSe)(dppe)2](dppe=Ph2 PCH2 CH2 PPh2  

Baek, Ji Yeong (Department of Chemistry (BK21), Sungkyunkwan University)
Han, Won Seok (Department of Chemistry (BK21), Sungkyunkwan University)
Lee, Sun Won (Department of Chemistry (BK21), Sungkyunkwan University)
Publication Information
Journal of the Korean Chemical Society / v.46, no.5, 2002 , pp. 427-436 More about this Journal
Abstract
Reaction of $trans-[FeHCl(dppe)_2]$ (1) with KSeCN led to the formation of $trans-[FeH(NCSe)(dppe)_2](2).$ Compound 2 $·CH_2Cl_2$ was structurally characterized by X-ray diffraction, in which the hydride ligand appears to be involved in the dihydrogen bonding of the type M-H${\cdot}$${\cdot}$${\cdot}$H-C.
Keywords
trans-[FeH(NCSe)$(dppe)_{2}$; Dihydrogen Bonding; M-H${\cdot}$${\cdot}$${\cdot}$H-C;
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