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http://dx.doi.org/10.5012/bkcs.2014.35.9.2769

Synthesis of POSS Derived Organic-Inorganic Hybrid Esters for Insulating Oil Applications  

Choi, Kyeong-Min (Departments of Chemistry and Physics, Changwon National University)
Harshavardhan, S.J. (Departments of Chemistry and Physics, Changwon National University)
Sridhar, Ch. (Departments of Chemistry and Physics, Changwon National University)
Vijaykumar, B.V.D. (Departments of Chemistry and Physics, Changwon National University)
Kumar, Deepak (Departments of Chemistry and Physics, Changwon National University)
Jang, Kiwan (Departments of Chemistry and Physics, Changwon National University)
Lee, Man-Sig (Green Technology Center, Korea Institute of Industrial Technology (KITECH))
Shin, Dong-Soo (Departments of Chemistry and Physics, Changwon National University)
Publication Information
Bulletin of the Korean Chemical Society / v.35, no.9, 2014 , pp. 2769-2773 More about this Journal
Abstract
In this work, a new family of polyhedral oligomeric silsesquioxanes (POSS) based esters have been synthesized that consists eight ester functional groups. These are classified into Type-I and Type-II esters based on the starting materials, octakis(3-chloropropyl)silsesquioxane (Cl-POSS) and octakis(3-hydroxypropyldimethylsiloxy) octasilsesquioxane (OHPS) respectively. These new POSS type ester moieties can be used as insulating oils and oil additives in the transformers and also considered to be alternatives to mineral and vegetable oils that are presently used in the insulation system.
Keywords
POSS esters; Esterification; Insulating oils;
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