[KSCI] Korea Science Citation Index Service

http://dx.doi.org/10.5012/bkcs.2014.35.9.2669

Selective Synthesis of Butene-1 Through Double-bond Migration of Butene-2 over η-Alumina Catalysts

Jeon, Jong-Ki (Department of Chemical Engineering, Kongju National University)
Kim, Do Heui (School of Chemical and Biological Engineering, Seoul National University)
Park, Young-Kwon (School of Environmental Engineering, University of Seoul)

Publication Information

Bulletin of the Korean Chemical Society / v.35, no.9, 2014 , pp. 2669-2672 More about this Journal

Abstract

Double bond migration of butene-2 to butene-1 over ${\eta}$ -alumina was investigated. The effects of calcination temperature on catalytic properties were analyzed by applying BET surface area, XRD, $NH_3$ -TPD, and FT-IR of adsorbed pyridine techniques. The highest activity of the ${\eta}$ -alumina catalyst calcined at $600^{\circ}C$ could be attributed not only to the highest amount of weak and medium strength acid sites, but also to the highest ratio of medium to weak strength Lewis acid sites.

Keywords

Butene-2; Double bond migration; ${\eta}$ -Alumina catalyst; Butene-1; Acid sites;

Citations & Related Records

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