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http://dx.doi.org/10.5012/bkcs.2014.35.8.2477

Simple Preparation of Anatase Titanium Dioxide Nanoparticles by Heating Titanium-Organic Frameworks  

Im, Ji Hyuk (Carbon Nanomaterials Design Laboratory, Global Research Laboratory, Research Institute of Advanced Materials, and Department of Materials Science and Engineering, Seoul National University)
Kang, Eunyoung (Institute for Integrative Basic Sciences, Department of Chemistry, Soongsil University)
Yang, Seung Jae (Carbon Nanomaterials Design Laboratory, Global Research Laboratory, Research Institute of Advanced Materials, and Department of Materials Science and Engineering, Seoul National University)
Park, Hye Jeong (Institute for Integrative Basic Sciences, Department of Chemistry, Soongsil University)
Kim, Jaheon (Institute for Integrative Basic Sciences, Department of Chemistry, Soongsil University)
Park, Chong Rae (Carbon Nanomaterials Design Laboratory, Global Research Laboratory, Research Institute of Advanced Materials, and Department of Materials Science and Engineering, Seoul National University)
Publication Information
Bulletin of the Korean Chemical Society / v.35, no.8, 2014 , pp. 2477-2480 More about this Journal
Abstract
Thermal degradation of titanium-containing metal-organic frameworks (MOFs; MIL-125 and MIL-125-$NH_2$ at $350^{\circ}C$ for 6 h in air produced $TiO_2$ nanoparticles of ca. 10 nm in diameter. Scanning electron and transmission electron microscope analyses indicated that those nanoparticles were aggregated randomly within each crystalline particle of their MOF precursors. The $TiO_2$ nanoparticles prepared from MIL-125-$NH_2$ exhibited higher activity for the degradation of 4-chlorophenol under visible light.
Keywords
Metal-organic frameworks; Thermolysis; Titanium dioxide; Nanoparticles; MIL-125;
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