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http://dx.doi.org/10.5012/bkcs.2014.35.7.1989

Synthesis of Novel Chiral Diamino Alcohols and Their Application in Copper-Catalyzed Asymmetric Allylic Oxidation of Cycloolefins  

Faraji, Laleh (Department of Chemistry, Shahid Beheshti University)
Samadi, Saadi (Department of Chemistry, Shahid Beheshti University)
Jadidi, Khosrow (Department of Chemistry, Shahid Beheshti University)
Notash, Behrouz (Department of Chemistry, Shahid Beheshti University)
Publication Information
Bulletin of the Korean Chemical Society / v.35, no.7, 2014 , pp. 1989-1995 More about this Journal
Abstract
The small library of new enantiomerically pure (S,S)-diamino alcohols 1 and their hydroxyldiamide precursors 2 were conveniently synthesized on a gram scale from inexpensive and commercially chiral pool amino acids. The catalytic and induced asymmetric effects of the chiral ligands 1 in the asymmetric allylic oxidation of cycloolefins were investigated.
Keywords
Chiral diamino alcohols; Chiral hydroxyldiamides; Asymmetric allylic oxidation; Small chiral libraries; Chiral pool amino acids;
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