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http://dx.doi.org/10.5012/bkcs.2014.35.2.525

Fabrication and Characterization of Titanate Nanotube Supported ZSM-5 Zeolite Composite Catalyst for Ethanol Dehydration to Ethylene  

Wu, Liangpeng (Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences)
Li, Xinjun (Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences)
Yuan, Zhenhong (Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences)
Chen, Yong (Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences)
Publication Information
Bulletin of the Korean Chemical Society / v.35, no.2, 2014 , pp. 525-530 More about this Journal
Abstract
Titanium dioxide nanotube supported ZSM-5 zeolite composite catalyst was fabricated by decorating ZSM-5 zeolite on the hydrothermally synthesized titanium dioxide via hydrothermal process and subsequent annealing. The catalyst was characterized by X-ray powder diffraction (XRD), Transmission electron microscopy (TEM) and Nitrogen adsorption-desorption (BET). The surface acidity of the catalyst was measured by means of Fourier transform infrared (FT-IR) spectrum of pyridine adsorption. And the catalytic activity for ethanol dehydration to ethylene was evaluated in a continuous flow fixed-bed reactor. Attributed to the increase of the effective surface acid sites caused by titanium dioxide nanotube as electron acceptor, titanium dioxide nanotube supported ZSM-5 zeolite composite catalyst exhibits strongly enhanced activity for ethanol dehydration to ethylene.
Keywords
ZSM-5 zeolite; $TiO_2$ nanotube; Ethanol; Dehydration; Ethylene;
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