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http://dx.doi.org/10.5012/bkcs.2014.35.11.3213

Oxidation of Ethylbenzene Using Nickel Oxide Supported Metal Organic Framework Catalyst  

Peng, Mei Mei (Department of Chemical Engineering, Hanseo University)
Jeon, Ung Jin (Department of Chemical Engineering, Hanseo University)
Ganesh, Mani (Department of Chemical Engineering, Hanseo University)
Aziz, Abidov (Department of Chemical Engineering, Hanseo University)
Vinodh, Rajangam (Department of Chemical Engineering, Hanseo University)
Palanichamy, Muthiahpillai (Department of Chemical Engineering, Hanseo University)
Jang, Hyun Tae (Department of Chemical Engineering, Hanseo University)
Publication Information
Bulletin of the Korean Chemical Society / v.35, no.11, 2014 , pp. 3213-3218 More about this Journal
Abstract
A metal organic framework-supported Nickel nanoparticle (Ni-MOF-5) was successfully synthesized using a simple impregnation method. The obtained solid acid catalyst was characterized by Powder X-ray diffraction (XRD), scanning electron microscopy (SEM), nitrogen adsorption-desorption and thermogravimetric analysis (TGA). The catalyst was highly crystalline with good thermodynamic stability (up to $400^{\circ}C$) and high surface area ($699m^2g^{-1}$). The catalyst was studied for the oxidation of ethyl benzene, and the results were monitored via gas chromatography (GC) and found that the Ni-MOF-5 catalyst was highly effective for ethyl benzene oxidation. The conversion of ethyl benzene and the selectivity for acetophenone were 55.3% and 90.2%, respectively.
Keywords
Solid catalyst; MOFs; Ni-MOF-5; Oxidation reaction; Ethylbenzene;
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