Browse > Article
http://dx.doi.org/10.5012/bkcs.2014.35.11.3163

Lanthanum Oxide-catalyzed Transesterification of Dimethyl Carbonate with Glycerol: Effect of Surfactant  

Lim, Seung Rok (Department of Chemistry and Basic Research Institute of Science, Kyung Hee University)
Lee, Sang Deuk (Clean Energy Research Center, Korea Institute of Science and Technology)
Kim, Hoon Sik (Department of Chemistry and Basic Research Institute of Science, Kyung Hee University)
Simanjuntak, Fidelis Stefanus Hubertson (Clean Energy Research Center, Korea Institute of Science and Technology)
Lee, Hyunjoo (Clean Energy Research Center, Korea Institute of Science and Technology)
Publication Information
Bulletin of the Korean Chemical Society / v.35, no.11, 2014 , pp. 3163-3168 More about this Journal
Abstract
Three kinds of lanthanum oxides ($La_2CO_3$) were synthesized from different methods and used as a catalyst in the transesterification of dimethyl carbonate (DMC) with glycerol for the synthesis of glycerol carbonate (GLC). Lanthanum oxide synthesized using a surfactant (S-La) showed a much higher GLC yield of 89.9% compared to other lanthanum oxides synthesized by calcination (C-La) and precipitation (P-La) at the reaction conditions of $90^{\circ}C$, DMC/glycerol = 2, and catalyst/glycerol = 5 wt %. The best catalyst was obtained when the surfactant/La weight ratio was 12. XRD study revealed that S-La has large amount of monoclinic and hexagonal $La_2O_2CO_3$ phases, which are assumed as active sites of the catalyst for the reaction.
Keywords
Glycerol; Dimethyl carbonate; Glycerol carbonate; Lanthanum oxide; Surfactant;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Huang, P.; Zhao, Y.; Zhang, J.; Zhu, Y.; Sun, Y. Nanoscale 2013, 5, 10844.   DOI   ScienceOn
2 Imanaka, N.; Okamoto, K.; Adachi, N. G. Electrochem. Commun. 2001, 3, 49.   DOI   ScienceOn
3 Yang, J. C.; Nie, Z. R.; Wang, Y. M. Appl. Surf. Sci. 2003, 215, 87.   DOI   ScienceOn
4 Wang, S.; Wang, W.; Qian, Y. Thin Solid Films 2000, 372, 50.   DOI   ScienceOn
5 Chen, W.; Kang, Z.; Ding, B. Mater Lett. 2005, 59, 1138.   DOI   ScienceOn
6 Taylor, R.; Schrader, G. Ind. Eng. Chem. Res. 1991, 30, 1016.   DOI
7 Fukuda, Y.; Hattori, H.; Tanabe, K. Bull. Chem. Soc. Jpn. 1978, 51, 3150.   DOI   ScienceOn
8 Imizum, Y.; Sato, K.; Hattori, H. J. Catal. 1982, 76, 65.   DOI   ScienceOn
9 Valange, S.; Beauchaud, A.; Barrault, J.; Gabelica, Z.; Daturi, M.; Can, F. J. Catal. 2007, 251, 113.   DOI   ScienceOn
10 Mentus, S.; Jeli, D.; Grudic, V. J. Therm. Anal. Calorim. 2007, 90, 393.   DOI
11 Ozawa, M.; Onoe, R.; Kato, H. J. Alloy Comp. 2006, 408-412, 556.   DOI   ScienceOn
12 Zhang, N.; Yi, R.; Zhou, L. B.; Gao, G. H.; Shi, R. G. Mater. Chem. Phys. 2009, 114, 160.   DOI
13 Tang, B.; Ge, J.; Wu, C.; Zhuo, L.; Niu, J.; Chen, Z.; Shi, Z.; Dong, Y. Nanotechnology 2004,15, 1273.   DOI   ScienceOn
14 Frey, A. M.; Bitter, J. H.; de Jong, K. P. ChemCatChem. 2010, 3, 1193.
15 Simanjuntak, F. S. H.; Tanda, V. T.; Kim, C. S.; Ahn, B. S.; Kim, Y. J.; Lee, H. Chem. Eng. Sci. 2013, 94, 265.   DOI   ScienceOn
16 Frey, A. M.; Karmee, S. K.; Bitter, J. H.; de Jong, K. P.; Hanefeld, U. ChemCatChem. 2013, 5, 594.   DOI
17 Randall, D.; De Vos, R. Eur. Patent EP 419114, 1991.
18 Kim, M.; Maggio, C. D.; Yan, S.; Salley, S. O.; Ng, K. Y. S. Green Chem. 2011, 13, 334.   DOI
19 Mu, Q. Y.; Wang, Y. D. J. Alloys Compd. 2011, 509, 396.   DOI   ScienceOn
20 Huntsman Corporation, $JEFFSOL{(R)}$ Glycerine Carbonate, 2009, http://www.huntsman.com/performance_products/Media/JEFFSOL%20Glycerine%20Carbonate.pdf.
21 Rokicki, G.; Rakoczy, P.; Parzuchowski, P.; Sobiecki, M. Green Chem. 2005, 7, 529.   DOI   ScienceOn
22 Climent, M. J.; Corma, A.; De Fruto, P.; Iborra, S.; Noy, M.; Velty, A.; Concepcion, P. J. Catal. 2010, 269, 140.   DOI   ScienceOn
23 Ubaghs, L.; Fricke, N.; Keul, H.; Hocker, H. Macromol. Rapid Commun. 2004, 25, 517.   DOI   ScienceOn
24 Aresta, M.; Dibenedetto, A.; Nocito, F.; Pastore, C. J. Mol. Catal. A: Chem. 2006, 257, 149.   DOI   ScienceOn
25 Aresta, M.; Dibenedetto, A.; Nocito, F.; Ferragina, C. J. Catal. 2009, 268, 106.   DOI   ScienceOn
26 Hu, J.; Li, J.; Gu, Y.; Guan, Z.; Mo, W.; Ni, Y. Li, T.; Li, G. Appl. Catal. 2010, 386, 188.   DOI   ScienceOn
27 Ochoa-Gomez, J. R.; Gomez-Jimenez-Aberasturi, O.; Maestro- Madurga, B.; Pesquera-Rodriguez, A.; Ramirez-Lopez, C.; Lorenzo-Ibarreta, L.; Torrecilla-Soria, J.; Villaran-Velasco, M. C. Appl. Catal. A 2009, 366, 315.   DOI   ScienceOn
28 Simanjuntak, F. S. H.; Kim, T. K.; Lee, S. D.; Ahn, B. S.; Kim, H. S.; Lee, H. Appl. Catal. A 2011, 401, 220.   DOI   ScienceOn
29 Taylor, R.; Schrader, G. Ind. Eng. Chem. Res. 1991, 30, 1016.   DOI
30 Takagaki, A.; Iwatana, K.; Nishimura, S.; Ebitani, K. Green Chem. 2010, 12, 578.   DOI   ScienceOn
31 Malyaadri, M.; Jagadeeswaraiah, K.; Sai Prasad, P. S.; Lingaiah, N. Appl. Catal. A 2011, 401, 153.   DOI   ScienceOn
32 Kijenski, J.; Radomski, P.; Fedorynska, E. J. Catal. 2001, 203, 407.   DOI   ScienceOn
33 Ochoa-Gomez, J. R.; Gomez-Jimenez-Aberasturi, O.; Ramirez-Lopez, C.; Maestro-Madurga, B. Green Chem. 2012, 14, 3368.   DOI   ScienceOn
34 Neumann, A.; Walter, D. Thermochim. Acta 2006, 445, 200.   DOI   ScienceOn
35 Weuthen, M.; Hees, U. Ger. Patent DE 4335947, 1995.
36 Park, J.; Choi, J. S.; Woo, S. K.; Lee, S. D.; Cheong, M.; Kim, H. S.; Lee, H. Appl. Catal. A 2012, 433-434, 35.   DOI   ScienceOn