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http://dx.doi.org/10.5012/bkcs.2014.35.10.3063

Synthesis of Poly(N-methylol Methacrylamide/Vinyl Sulfonic Acid) Hydrogels for Heavy Metal Ion Removal  

Yakar, Arzu (Afyon Kocatepe University, Faculty of Engineering, Department of Chemical Engineering)
Publication Information
Bulletin of the Korean Chemical Society / v.35, no.10, 2014 , pp. 3063-3070 More about this Journal
Abstract
In this study, poly(N-methylol methacrylamide) (NMMAAm) and poly(N-methylol methacrylamide/vinyl sulphonic acid) (NMMAAm-VSA) hydrogels were synthesized by $^{60}Co-{\gamma}$ ray irradiation at an ambient temperature. The graphs belonging to the gelation percent- percent-dose and swelling curves were drawn by using data which were obtained from water and different pH solutions. Characterization of hydrogels was performed by FTIR and DSC-TGA analysis. Heavy metal ion ($Ni^{2+}$, $Co^{2+}$) removal capacities of hydrogels were investigated in aqueous solutions, which had different concentrations (100-1500 mg/L). In metal ion removal studies, pH value of aqueous medium was kept constant at 5.0. Maximum metal ion removal values were obtained for NMMAAm-VSA (1:3 mole ratio) hydrogels. Metal ion removal capacities of NMMAAm-VSA (1:3 mole ratio) hydrogels were found as 82 mg/g and 98 mg/g for $Ni^{2+}$ and $Co^{2+}$ ions, respectively.
Keywords
Acrylamide type hydrogels; Vinyl sulphonic acid; Gamma irradiation; Adsorption;
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  • Reference
1 Nickel and Nickel Compounds, State of Ohio Environmental Protection Agency Pollution Prevention Fact Sheet, September, Number 96, 2002.
2 Bessbousse, H.; Rhlalou, T.; Verchere, J.-F.; Lebrun, L. J. Membr. Sci. 2008, 307, 249.   DOI   ScienceOn
3 Hook, A. L.; Thissen, H.; Quinton, J.; Voelcker, N. H. Surf. Sci. 2008, 62, 1883.
4 Arova, M. K.; Zuki, F. M.; Sulaiman, N. M. J. Hazard. Mater. 2007, 147, 752.   DOI   ScienceOn
5 Metilda, P.; Prasad, K.; Kala, R.; Gladis, J. M.; Rao, T. P.; Naidu, G. R. K. Anal. Chim. Acta 2007, 582, 147.   DOI
6 Okieimen, F. E.; Sogbaike, C. E.; Ebhoaye, J. E. Sep. Purif. Technol. 2005, 44, 85.   DOI   ScienceOn
7 He, C.; Kim, S. W.; Lee, D. S. J. Control. Release 2008, 127, 189.   DOI   ScienceOn
8 Van Tomme, S. R.; Storm, G.; Hennink, W. E. Int. J. Pharm. 2008, 355, 1.   DOI
9 Ripin, D. H.; Evans, D. A. Chem. 206, http://evans.harvard.edu.
10 Skoog, D. A.; West, D. M.; Holler, F. J. Fundamentals of Analytical Chemistry, 5th ed.; Saunders College Publishing: USA, 1988; p 383.
11 Pekel, N.; Güven, O. Polym. Int. 2002, 51, 1404.   DOI
12 Sen, M.; Yakar, A. Int. J. Pharm. 2001, 228, 33.   DOI
13 Klattenhoff, D.; Escobar, R.; Aliste, E. J. Chil. Chem. Soc. 2006, 51, 887.
14 Kim, S. J.; Park, S. J.; Kim, S. I. Smart. Mater. Struct. 2004, 13, 317.   DOI
15 Pourjavadi, A.; Ghasemzadeh, H. Polym. Eng. Sci. 2007, 47, 1388.   DOI   ScienceOn
16 Kim, S. J.; Park, S. J.; Kim, S. I. Smart. Mater. Struct. 2004, 13, 317.   DOI
17 Rabotyagova, O. S.; Cebe, P.; Kaplan, D. L. Mater. Sci. Eng. C Mater. Biol. Appl. 2008, 28, 1420.   DOI
18 Ozay, O.; Ekici, S.; Baran, Y.; Aktas, N.; Sahiner, N. Water. Res. 2009, 43, 4403.   DOI
19 Chiou, C. W.; Lin, Y. C.; Wang, L.; Hirano, C.; Suzuki, Y.; Hayakawa, T.; Kuo, S.W. Polymers 2014, 6, 926.   DOI
20 Stuart, B. Infrared Spectroscopy: Fundamentals and Applications; John Wiley & Sons: Ltd.: 2004.
21 Jiang, D. D.; Yao, Q.; McKinney, M. A.; Wilkie, C. A. Polym. Degrad. Stabil. 1999, 63, 423.   DOI
22 Huheey, J. E. Inorganic Chemistry, Principles of Structure and Reactivity; Harper Collins: London, 1993; p 114.
23 Li, Z.; Chang, X.; Hu, Z.; Huang, X.; Zou, X.; Wu, Q.; Nie, R. J. Hazard Mater. 2009, 166, 133.   DOI
24 Kasaini, H.; Kekana, P. T.; Saghti, A. A.; Bolton, K. World Academy of Science, Engineering and Technology 2013, 76, 707.
25 Bhattacharyya, K. G.; Sen Gupta, S. Appl. Clay. Sci. 2008, 41, 1.   DOI   ScienceOn
26 Bhattacharyya, K. G.; Sen Gupta, S. Appl. Clay. Sci. 2009, 46, 216.   DOI
27 Monier, M.; Wei, Y.; Sarhan, A. A. React. Funct. Polym. 2010, 70, 257.   DOI
28 Zainol, Z.; Nicol, M. J. Hydrometallurgy 2009, 99, 175.   DOI   ScienceOn
29 Kavaklı, C.; Tuncel, S. A.; Salih, B. Sep. Purif. Technol. 2005, 45, 32.   DOI
30 Farias, R. F.; Nascimento, A. A. S.; Bezerra, C. W. B. J. Colloid. Interface. Sci. 2004, 277, 19.   DOI
31 Giles, C. H.; McEwan, T. H.; Nakwa, S. N.; Smith, D. J. Chem. Soc. 1960, 4, 3973.
32 Langmuir, I. J. Am. Chem. Soc. 1918, 40, 1361.   DOI
33 Cobalt and Inorganic cobalt compounds. Concise International Chemical Assessment Document 69, World Health Organization, 2006.
34 Singh, A.; Narvi, S. S.; Dutta, P. K.; Pandey, N. D. Bull. Mater. Sci. 2006, 29, 233.   DOI
35 Repoa, E.; Kurniawana, T. A.; Warcholb, J. K.; Sillanpaa, M. E. T. J. Hazard. Mater. 2009, 171, 1071.   DOI