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http://dx.doi.org/10.5012/bkcs.2013.34.8.2286

Efficient Ring Opening Reaction of Epoxides with Oxygen Nucleophiles Catalyzed by Quaternary Onium Salt  

Kim, Jin Won (Department of Chemistry, Yeungnam University)
Cho, Dae Won (Department of Chemistry, Yeungnam University)
Park, Gyoosoon (Department of Chemistry, Kookmin University)
Kim, Sung Hong (Analysis Research Division, Daegu Center, Korea Basic Science Institute)
Ra, Choon Sup (Department of Chemistry, Yeungnam University)
Publication Information
Bulletin of the Korean Chemical Society / v.34, no.8, 2013 , pp. 2286-2290 More about this Journal
Abstract
Ring opening reactions of epoxides with oxygen nucleophiles catalyzed by a variety of quaternary onium salt, such as ammonium or phosphonium salt were explored. The results showed that tetrabutylphosphonium bromide (TBPB) among salts serves as the most efficient catalyst for this process and that expoxide ring opening reactions with a variety of oxygen nucleophiles including carboxyic acid and phenol, promoted using this salt, lead to generate readily purifiable products in excellent yields.
Keywords
Ring opening reaction; Epoxide; Oxygen nucleophile; Quaternary onium salt;
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