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http://dx.doi.org/10.5012/bkcs.2013.34.8.2261

An off-on Fluorescent Sensor for Detecting a Wide Range of Water Content in Organic Solvents  

Kim, Kang-Hyeon (School of Applied Chemical Engineering, Chonnam National University)
Lee, Wan-Jin (School of Applied Chemical Engineering, Chonnam National University)
Kim, Jae Nyoung (Department of Chemistry and Institute of Basic Science, Chonnam National University)
Kim, Hyung Jin (School of Applied Chemical Engineering, Chonnam National University)
Publication Information
Bulletin of the Korean Chemical Society / v.34, no.8, 2013 , pp. 2261-2266 More about this Journal
Abstract
This paper describes the synthesis and water sensing properties of a fluorescent photoinduced electron transfer (PET) sensor (5) with an extended operating sensing range. The 1,8-naphthalimide derivative (5) attached with a piperazine group and a carboxylic group was synthesized and applied as a fluorescent water sensor in water-miscible organic solvents. The fluorescence intensity of the dye 5 increased with increasing water content up to 80% (v/v) and the fluorescence intensities were enhanced 45-, 67- and 122-fold in aqueous EtOH, DMF and DMSO solutions, respectively. In aqueous acetone solution, the enhancement of the fluorescence intensities was somewhat lower (30-fold) but the response range was wider (0-90%, v/v).
Keywords
1,8-Naphthalimide; Water sensor; Fluorescent sensor; Photoinduced electron transfer; PET;
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