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http://dx.doi.org/10.5012/bkcs.2013.34.7.1995

Preparation and Cyclic Performance of Li1.2(Fe0.16Mn0.32Ni0.32)O2 Layered Cathode Material by the Mixed Hydroxide Method  

Karthikeyan, K. (Faculty of Applied Chemical Engineering, Chonnam National University)
Nam, K.W. (Chemistry Department, Brookhaven National Laboratory)
Hu, E.Y. (Chemistry Department, Brookhaven National Laboratory)
Yang, X.Q. (Chemistry Department, Brookhaven National Laboratory)
Lee, Y.S. (Faculty of Applied Chemical Engineering, Chonnam National University)
Publication Information
Bulletin of the Korean Chemical Society / v.34, no.7, 2013 , pp. 1995-2000 More about this Journal
Abstract
Layered $Li_{1.2}(Fe_{0.16}Mn_{0.32}Ni_{0.32})O_2$ was prepared by the mixed hydroxide method at various temperatures. Xray diffraction (XRD) pattern shows that this material has a ${\alpha}-NaFeO_2$ layered structure with $R{\bar{3}}m$ space group and that cation mixing is reduced with increasing synthesis temperature. Scanning electron microscopy (SEM) reveals that nano-sized $Li_{1.2}(Fe_{0.16}Mn_{0.32}Ni_{0.32})O_2$ powder has uniform particle size distribution. X-ray absorption near edge structure (XANES) analysis is used to study the local electronic structure changes around the Mn, Fe, and Ni atoms in this material. The sample prepared at $700^{\circ}C$ delivers the highest discharge capacity of 207 $mAhg^{-1}$ between 2-4.5 V at 0.1 $mAcm^{-2}$ with good capacity retention of 80% after 20 cycles.
Keywords
Mixed hydroxide method; Lithium Mn oxide; XANES; Layered materials; Lithium batteries;
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