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http://dx.doi.org/10.5012/bkcs.2013.34.5.1508

A Fast, Highly Efficient and Green Protocol for One-Pot Synthesis of 2,4,5-Trisubstituted Imidazoles Catalyzed by [TBA]2[W6O19] as a Reusable Heterogeneous Catalyst  

Ashrafi, Mozhgan (Department of Chemistry, Mashhad Branch, Islamic Azad University)
Davoodnia, Abolghasem (Department of Chemistry, Mashhad Branch, Islamic Azad University)
Tavakoli-Hoseini, Niloofar (Department of Chemistry, Mashhad Branch, Islamic Azad University)
Publication Information
Bulletin of the Korean Chemical Society / v.34, no.5, 2013 , pp. 1508-1512 More about this Journal
Abstract
A simple and efficient synthesis of 2,4,5-trisubstituted imidazoles was achieved via a one-pot three-component cyclocondensation of benzil, aromatic aldehydes, and ammonium acetate in the presence of a catalytic amount of tetrabutylammonium hexatungstate $[TBA]_2[W_6O_{19}]$ as a heterogeneous catalyst under thermal solvent-free conditions. The key features of this methodology are operational simplicity, high yields, short reaction times, and a recyclable catalyst with a very easy work up.
Keywords
Heterogeneous catalysis; Solvent-free conditions; Tetrabutylammonium hexatungstate $[TBA]_2[W_6O_{19}]$; 2,4,5-Trisubstituted imidazoles;
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