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http://dx.doi.org/10.5012/bkcs.2013.34.4.1061

Tune Metal Ion Selectivity by Changing Working Solvent: Fluorescent and Colorimetric Recognition of Cu2+ by a Known Hg2+ Selective Probe  

Tang, Lijun (Department of Chemistry, Liaoning Key Laboratory for the Synthesis and Application of Functional Compounds, Bohai University)
Guo, Jiaojiao (Department of Chemistry, Liaoning Key Laboratory for the Synthesis and Application of Functional Compounds, Bohai University)
Huang, Zhenlong (Department of Chemistry, Liaoning Key Laboratory for the Synthesis and Application of Functional Compounds, Bohai University)
Publication Information
Bulletin of the Korean Chemical Society / v.34, no.4, 2013 , pp. 1061-1064 More about this Journal
Abstract
A known $Hg^{2+}$ selective rhodamine B derivatised probe 1 was reinvestigated as a colorimetric and fluorescent probe for $Cu^{2+}$ through changing the applied solvent media. Probe 1 exhibited good selectivity and sensitivity to $Cu^{2+}$ in $CH_3CN-H_2O$ (7:3, v/v, HEPES 10 mM, pH 7.0) solution with a detection limit of $9.74{\times}10^{-7}$ M. The $Cu^{2+}$ sensing event was proved to be irreversible through hydrolysis of 1 to release rhodamine B.
Keywords
$Cu^{2+}$ recognition; Fluorescence; Colorimetric; Rhodamine;
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