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http://dx.doi.org/10.5012/bkcs.2013.34.3.773

Synthesis and Characterization of 1-D BiSI and 2-D BiOI Nanostructures  

Lee, Juheon (Department of Chemistry, Yeungnam University)
Min, Bong-Ki (Center for Research Facilities, Yeungnam University)
Cho, Insu (Department of Chemistry, Yeungnam University)
Sohn, Youngku (Department of Chemistry, Yeungnam University)
Publication Information
Bulletin of the Korean Chemical Society / v.34, no.3, 2013 , pp. 773-776 More about this Journal
Abstract
We have prepared 1-D BiSI and 2-D BiOI nanostructures, and characterized them by scanning electron microscopy, transmission electron microscopy (TEM), X-ray diffraction crystallography, thermogravimetric analysis/differential scanning calorimetry, and UV-visible absorption. Here, we first report clear HR-TEM image of BiSI. In addition, we first found that the growth direction of BiSI is [12-1] plane, with the neighboring distance of 0.30 nm. The crystal structures of BiSI and BiOI are found to be orthorhombic (Pnam) and tetragonal (P4/nmm), respectively. The absorption band gaps of BiSI and BiOI are measured to be 1.55 and 1.92 eV, respectively. Our study could further highlight the applications of V-VI-VII compounds.
Keywords
BiSI; BiOI; Growth direction; TEM; Band-gap;
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