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http://dx.doi.org/10.5012/bkcs.2013.34.2.374

Synthesis, Crystal Structures and Properties of Two Binuclear Supramolecular Complexes Based on Biphenyl-2,2'-dicarboxylic Acid Ligand  

Tang, Jin-Niu (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities)
Pan, Gang-Hong (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities)
Li, Long (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities)
Tian, Wei-Man (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities)
Huang, Zhong-Jing (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities)
Publication Information
Bulletin of the Korean Chemical Society / v.34, no.2, 2013 , pp. 374-378 More about this Journal
Abstract
Two novel binuclear metal-organic coordination complexes [$Cd_2(Hdpa)_4(bpy)_2$] (1), [$Dy_2(dpa)_2(bpy)_2(NO_3)_2-(H_2O)_2$](bpy) (2) (where $H_2dpa$ = biphenyl-2,2'-dicarboxylic acid, bpy = 2,2'-bipyridine) have been synthesized under hydrothermal conditions and characterized by single crystal X-ray diffraction, spectral method (IR), elemental analysis (EA), powder X-ray diffraction (XRD), electronic spectra (UV-vis), fluorescent in the solid state and thermogravimetric analysis (TGA). Complexes 1-2 crystallizes isomorphously in the Triclinic space group P-1. The ${\pi}-{\pi}$ stacking interactions and hydrogen-bonds play a vital role in determining the crystal packing and construction of the extended 3-D supramolecular network.
Keywords
Biphenyl-2,2'-dicarboxylic acid; Single-crystal structure; ${\pi}-{\pi}$ Stacking;
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1 Ding, B. B.; Weng, Y. Q.; Mao, Z. W.; Lam, C. K.; Chen, X. M.; Ye, B. H. Inorg. Chem. 2005, 44, 8836.   DOI   ScienceOn
2 Sang, R. L.; Xu, L. Polyhedron 2006, 25, 2167.   DOI   ScienceOn
3 Wang, X. L.; Qin, C.; Wang, E. B. Cryst. Growth Des. 2006, 6,439.   DOI   ScienceOn
4 Ghosh, A. K.; Ghoshal, D.; Zangrando, E. Polyhedron 2007, 26, 4195.   DOI   ScienceOn
5 Yue, N. L. S.; Jennings, M. C.; Puddephatta, R. J. Eur. J. Inorg. Chem. 2007, 12, 1690.
6 Lee, W. Z.; Kang, Y. L.; Wang, T. L.; Su, C. C.; Kuo, T. S. Cryst. Growth Des. 2008, 8, 2614.   DOI   ScienceOn
7 Rueff, J.-M.; Pillet, S.; Claiser, N.; Bonaventure, G.; Souhassou, M.; Rabu, P. Eur. J. Inorg. Chem. 2002, 895.
8 Xu, X.-X.; Lu, Y.; Wang, E.-B.; Ma, Y.; Bai, X.-L. Cryst. Growth Des. 2006, 6, 2029.   DOI   ScienceOn
9 Wang, R. H.; Hong, M. C.; Luo, J. H.; Cao, R.; Weng, J. B. Chem. Commun. 2003, 1018.
10 Ye, B. H.; Tong, M. L.; Chen, X. M. Coord. Chem. Rev. 2005, 249, 545.   DOI   ScienceOn
11 Wang, R. H.; Hong, M. C.; Luo, J. H.; Cao, R.; Weng, J. B. Eur. J. Inorg. Chem. 2002, 2082.
12 Rueff, J.-M.; Pillet, S.; Claiser, N.; Bonaventure, G.; Souhassou, M.; Rabu, P. Eur. J. Inorg. Chem. 2002, 895.
13 Kumagai, H.; Inoue, K.; Kurmoo, M. Bull. Chem. Soc. Jpn. 2002, 75, 1283.   DOI   ScienceOn
14 Lu, J. Y.; Schauss, V. Inorg. Chem. Commun. 2003, 6, 1332.   DOI   ScienceOn
15 Chen, X. M.; Liu, G. F. Chem. Eur. J. 2002, 8, 4811.   DOI
16 Zhang, X. M.; Tong, M. L.; Chen, X. M. Angew. Chem. Int. Ed. 2002, 41, 1029.   DOI
17 Tong, M. L.; Kitagawa, S.; Chang, H. C.; Ohba, M. Chem. Commun. 2004, 418.
18 Zheng, S. L.; Zhang, J. P.; Wong, W. T.; Chen, X. M. J. Am. Chem. Soc. 2003, 125, 6882.   DOI   ScienceOn
19 Zhang, X. M.; Tong, M. L.; Gong, M. L.; Lee, H. K.; Luo, L.; Li, J. H.; Tong, Y. X.; Chen, X. M. Chem. Eur. J. 2002, 8, 3187.   DOI
20 Sun, D. F.; Cao, R.; Sun,Y. Q.; Bi, W. H.; Li, X. J.; Wang, Y. Q.; Shi, Q.; Li, X. Inorg. Chem. 2003, 42, 7512.   DOI   ScienceOn
21 Xia, C. K.; Lu, C. Z.; Zhang, Q. Z.; He, X.; Zhang, J. J.; Wu, D. M. Cryst. Growth Des. 2005, 5, 1569.   DOI   ScienceOn
22 Blake, A. J.; Champness, N. R.; Hubberstey, P.; Li, W. S.; Withersby, M. A.; Schroder, M. Coord. Chem. Rev. 1999, 183, 117.   DOI   ScienceOn
23 Tadokoro, M.; Isobe, K.; Uekusa, H.; Ohashi, Y.; Toyoda, J.; Tashiro, K.; Nakasuji, K. Angew. Chem., Int. Ed. 1999, 38, 95.   DOI
24 Sheldrick, G. M. SHELXTL V5.1 software reference manual. Bruker AXS, Inc, Madison, Wisconsin, USA, 1997.
25 Liu, G. F.; Ye, B. H.; Ling, Y. H.; Chen, X. M. Chem. Commun. 2002, 1442.
26 Sheldrick, G. M. SADABS. Program for empirical absorption correction of area detector. University of Gottingen, Germany, 1996.